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ChemicalBook Optimization Suppliers |
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Struchem Co., Ltd. Gold |
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| | トリス(ジベンジリデンアセトン)(クロロホルム)ジパラジウム(0) 製品概要 |
| 化学名: | トリス(ジベンジリデンアセトン)(クロロホルム)ジパラジウム(0) | | 英語化学名: | Tris(dibenzylideneacetone)dipalladium-chloroform adduct | | 别名: | TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0);TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT;DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT;DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX;Dipalladiumtris(dibenzylideneacetone) chloroform adduct;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+%;Tris(dibenylideneacetone)dipalladium-chloroform;Tris (dibenzylidene acetone)di palladiuM(O)-chloroforM addict | | CAS番号: | 52522-40-4 | | 分子式: | C52H31Cl3O3Pd2 | | 分子量: | 1023.01 | | EINECS: | 610-856-2 | | カテゴリ情報: | organometallic complexes;Metal Compounds | | Mol File: | 52522-40-4.mol |  |
| | トリス(ジベンジリデンアセトン)(クロロホルム)ジパラジウム(0) 物理性質 |
| 融点 | 131-135 °C(lit.) | | 貯蔵温度 | Keep in dark place,Sealed in dry,Room Temperature | | 外見 | Crystalline Powder | | 色 | Purple to black | | 水溶解度 | Soluble in organic solvents. Insoluble in water. | | Sensitive | Air & Moisture Sensitive | | InChIKey | NLYJPAJWGANOKG-CXKPDERJSA-N |
| | トリス(ジベンジリデンアセトン)(クロロホルム)ジパラジウム(0) Usage And Synthesis |
| 外観 | 紫色～黒色, 結晶性粉末～粉末 | | 使用上の注意 | アルゴン封入 | | 化学的特性 | purple to black crystalline powder | | 使用 | Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct is a catalyst that is used in the preparation of anticancer activity of amino vinylindoles via palladium catalyzed coupling of hydrazone, haloindoles and amines. | | 使用 | suzuki reaction | | 主な応用 | Tris(dibenzylideneacetone)dipalladium-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
As cyclization catalyst.
As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.
| | 一般的な説明 | Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst. | | 生物活性 | N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst. |
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