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| | UiO-66-NH2(Zr) Basic information | | Uses |
| Product Name: | UiO-66-NH2(Zr) | | Synonyms: | ZIRCONIUMAMINOBENZENEDICARBOXYLATEMOF(UIO-66-BDC-NH2,BDC-NH2:ZR=0.9-1.0);NH2-UIO-66(Zr);Zirconium aminobenzenedicarboxylate MOF;UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0,Zirconium aminobenzenedicarboxylate MOF;NH2-UiO-66;UIO-66-NH2;MOF:UiO-66(Zr)-NH2;UiO-66-NH2(Zr) | | CAS: | 1260119-00-3 | | MF: | C48H30N6O32Zr6 | | MW: | 1750.12 | | EINECS: | | | Product Categories: | MOF | | Mol File: | 1260119-00-3.mol |  |
| | UiO-66-NH2(Zr) Chemical Properties |
| form | solid | | color | Yellow | | InChI | InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12 | | InChIKey | SGCQKKMGUIJGFK-UHFFFAOYSA-B |
| | UiO-66-NH2(Zr) Usage And Synthesis |
| Uses | Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0) Useful MOF for adsorption of CO2 applications
Catalyst MOF used in the conversion of toxic agents to non-toxic products
| | Definition |
UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].
| | References | [1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197. |
| | UiO-66-NH2(Zr) Preparation Products And Raw materials |
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