炭酸カルシウム(II)(1:1)(1317-65-3)

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炭酸カルシウム(II)(1:1) 製品概要
化学名:炭酸カルシウム(II)(1:1)
英語化学名:CALCIUM CARBONATE
别名:PARIS WHITE;CALCIUM CARBONATE 325;WHITING;lime stones;CHALK, PRECIPITATED;ENGLISH WHITE;KALKSPAR;ICELAND SPAR
CAS番号:1317-65-3
分子式:CCaO3
分子量:100.09
EINECS:215-279-6
カテゴリ情報:
Mol File:1317-65-3.mol
炭酸カルシウム(II)(1:1)
炭酸カルシウム(II)(1:1) 物理性質
融点 825 °C
沸点 2850 °C
比重(密度) 2.93 g/mL at 25 °C(lit.)
溶解性5 M HCl: 0.1 M at 20 °C, clear, colorless
外見 random crystals
Gray
Ksp溶解度積定数pKsp: 8.47
CAS データベース1317-65-3(CAS DataBase Reference)
EPAの化学物質情報Limestone (1317-65-3)
安全性情報
主な危険性 Xi
Rフレーズ 37/38-41
Sフレーズ 26-36/37/39
WGK Germany -
RTECS 番号FF9335000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
炭酸カルシウム(II)(1:1) Usage And Synthesis
定義本品は、主として炭酸カルシウムからなる鉱物である。
解説

あられ石,CaCO3よりなる鉱物.空間群 Pmcnの斜方晶系.格子定数 a0 = 0.496,b0 = 0.796,c0 = 0.574 nm.単位格子中4個の基本組成を含む.硬度3.5~4.密度2.947 g cm-3.紫外線,X線,電子線により蛍光を発する.Caの一部はわずかにSr,Pb,Znで置換される.方解石と多形の関係にあるが不安定である.火成岩の晶洞,あるいは低温の地表,温泉地帯に産出する.

化粧品の成分用途皮膚コンディショニング剤
説明Calcite is one of the most common minerals on the face of the earth, comprising about 4% by weight of the earth’s crust and is formed in many different geological environments. Calcite can form rocks of considerable mass and constitutes a significant part of all three major rock classification types. It forms oolitic, fossiliferous and massive limestones in sedimentary environments and even serves as the internal cement for many sandstones and shales.Calcite is even a major component in the igneous rock called carbonatite and forms the major portion of many hydrothermal veins. Not necessarily a variety of calcite, cave formations are certainly a unique aspect of calcite’s story.
化学的特性Calcium carbonate is a white, odorless powder, or crystalline solid.
化学的特性Ground limestone consists essentially of calcium carbonate. It is obtained by crushing, grinding, and classifying naturally occurring limestone benefited by flotation and/or air classification. It is pro duced as a fine, white to off-white, microcrystalline powder. It is odorless and tasteless and is stable in air. It is practically insoluble in water and in alcohol. The presence of any ammonium salt or carbon dioxide increases its solubility in water, but the presence of any alkali hydroxide reduces the solubility.
使用Manufacture of quicklime, Portland cement, and paints. United States Pharmacopeia (USP) grades are used in dentifrices, cosmetics, food, and pharmaceuticals such as antacids.
使用Source of lime; neutralizing agent, filler, and extender in rubber, plastics, paints; opacifying agent in paper; fortification of bread; putty; tooth pow- ders; antacid; whitewash; Portland cement; sulfur dioxide removal from stack gases; metallurgical flux; analytical chemistry; carbon dioxide gener- ation (laboratory).
使用Calcite is the primary mineral component in cave formations. Stalactites and stalagmites, cave veils, cave pearls, “soda straws” and the many other different cave formations that millions of visitors to underground caverns enjoy are made of calcite.
製造方法The calcite present is derived mostly from the remains of organisms such as clams, brachiopods, bryozoa, crinoids and corals. These animals live on the bottom of the sea and when they die their shells accumulate into piles of shelly debris. This debris can then form beds of limestone. Some limestones may have been derived from nonbiogenic calcite formation.
定義Aragonite: An anhydrous mineral form of calcium carbonate, CaCO3, which occurs associated with limestone and in some metamorphic rocks. It is also the main ingredient of pearls. It is not as stable as calcite, into which it may change over time.
Calcite:A mineral form of calcium carbonate occurring in limestone, chalk, and marble.
Charlk: A natural form of calcium carbonate (CaCO3) formed originally by marine organisms. (Blackboard chalk is calcium sulfate, CaSO4.).
一般的な説明Odorless, white to tan powder.
反応プロフィールCALCIUM CARBONATE has generally low chemical reactivity. Is non-combustible. Decomposes at high temperature (825°C) to give gaseous carbon dioxide and calcium oxide (quicklime). Incompatible with acids, alum, ammonium salts, fluorine, magnesium. Reacts with acids and acidic salts to generate gaseous carbon dioxide with effervescence (bubbling). The reaction is rapid and exothermic with concentrated solutions of acids. The efferversence can create extensive foaming. Ignites on contact with fluorine.
危険性A nuisance particulate dust.
健康ハザードCalcium carbonate is considered to be a nuisance dust.
Although no adverse effects have been reported in the literature among workers exposed to calcium carbonate, high concentrations of the dust would be expected to act as a physical irritant to the eyes and skin.1 Fourteen British workers exposed to heavy calcium carbonate concentrations for 12–35 years showed no trace abnormalities due to dust or any clinical sign of pneumoconiosis or chronic bronchitis on X ray.2 Long exposure to high dust concentrations of pure calcium carbonate (quartz content less than 1.1%) did not result in lung fibrosis.
农业用途Limestone or dolomite, used in agriculture for liming the soil, is ground to a fineness to ensure that 50% of the particles pass through a 1.70mm Indian Standards (IS) sieve, and 50% is retained on a 150micron IS sieve.
安全性プロファイルA nuisance dust. An eye and skin irritant. Igmtes on contact with F2. Incompatible with acids, ammonium salts, (Mg + H2). Calcium carbonate is a common air contaminant. See also CALCIUM COMPOUNDS.
職業ばく露Calcium carbonate is used as a source of lime; neutralizing agent; manufacturing or rubber, plastics, paint and coatings; sealants, paper, dentifrices, ceramics, putty, polishes and cleaners, insecticides, inks and cosmetics; whitewash; Portland cement; antacids; analytical chemistry, and others
不和合性Calcium carbonate decomposes in high temperature forming carbon dioxide and corrosive materials
廃棄物の処理Landfills. It is the responsibility of chemical waste generators to determine if a discarded chemical is classified as a hazardous waste. See 40 CFR Parts 261.3 for United States Environmental Protection Agency guidelines for the classification determination. In addition, in order to ensure complete and accurate classification, waste generators must consult state and local hazardous waste regulations.
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