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(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]

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(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Suppliers list
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
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Products Intro: Product Name:(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
CAS:175166-49-1
Purity:99% Package:100g ;1KG ;5KG 25KG
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Products Intro: Product Name:(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
CAS:175166-49-1
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Products Intro: Product Name:(-)-2,2'-Methylenebis[(3as,8ar)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
CAS:175166-49-1
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Products Intro: Product Name:(-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole]
CAS:175166-49-1
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC11791
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Products Intro: Product Name:(3aS,3′aS,8aR,8′aR)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
CAS:175166-49-1
Purity:98% Package:$16.9/100mg;$33.9/250mg;$97.9/1g;$295.9/5g;Bulk package Remarks:98%
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Basic information
Product Name:(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
Synonyms:[3as-[2(3′Ar*,8′As*),3′AΑ,8′AΑ]]-()-2,2′-Methylenebis[3a,8a-Dihydro-8H-Inden;[3AS-[2(3'A R*,8'A S*),3'A-ALPHA,8'A-ALPHA]]-(-)-2,2'-METHYLENEBIS[3A,8A-DIHYDRO-8 H-INDENO[1,2-D]OXAZOLE];(-)-2,2'-Methylenebis;(3aS,3′aS,8aR,8′aR)-(-)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole];8H-Indeno[1,2-d]oxazole,2,2'-Methylenebis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)-;(-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%;[3AS-[2(3'A R*,8'A S*),3'A-ALPHA,8'A-ALPHA]]-(-)-2,2'-METHYLENEBIS[3A,8A-DIHYDRO-8 H-INDENO[1,2-D]OXAZOLE];(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
CAS:175166-49-1
MF:C21H18N2O2
MW:330.38
EINECS:
Product Categories:Asymmetric Synthesis;Synthetic Organic Chemistry;BOX;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;BOX series;Chiral Nitrogen
Mol File:175166-49-1.mol
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Structure
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Chemical Properties
Melting point 224 °C
Boiling point 493.2±45.0 °C(Predicted)
density 1.48±0.1 g/cm3(Predicted)
refractive index -360 ° (C=1, CH2Cl2)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility almost transparency in Dichloromethane
form powder to crystal
pka5.47±0.20(Predicted)
color White to Almost white
optical activity[α]22/D 355°, c = 3.7 in chloroform
InChIKeyBDHSVQLSNIGJNC-JYWFKMLOSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29349990
MSDS Information
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Usage And Synthesis
Chemical PropertiesWhite powder
Uses(3aS,3′aS,8aR,8′aR)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] can be used as a chiral ligand:
  • In the preparation of oxazole α-hydroxy esters through intermolecular Alder-Ene reaction.
  • In the atom transfer radical polymerization reactions of methyl methacrylate.
  • In the copper-catalyzed synthesis of isoxazolidine derivatives by reacting nitrone with α,β-unsaturated acyl?phosphonate.

(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Preparation Products And Raw materials
Preparation Products(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Diphenylpropane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole)
Tag:(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE](175166-49-1) Related Product Information
(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Diphenylpropane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole) (3aS,3'aS,8aR,8'aR)-2,2'-Cyclopentylidenebis[3a,8a-dihydr o-8H-indeno[1,2-d]oxazole] (3aR,3'aR,8aS,8'aS)-2,2'-Cyclopentylidenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] (+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] (3aR,3'aR,8aS,8'a'S)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole (3aR,3a'R,8aS,8a'S)-2,2'-(1,3-diphenylpropane-2,2-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole) (3aS,3'aS,8aR,8'a'R)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole Indene Trans-1-Amino-2-hydroxyindane 2-Indanol (R)-(-)-1-Aminoindan (1S,2R)-(-)-cis-1-Amino-2-indanol 2-Ethyl-2-oxazoline (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) 1-Aminoindan (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]