(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)

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(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) manufacturers
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) Basic information
Reaction
Product Name:(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)
Synonyms:(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%;(-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%;(R,R)-DACH-pyridyl Trost ligand;1R,2R- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide);2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine;(R,R)-DACH-pyridyl Trost ligand 95%;(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%
CAS:218290-24-5
MF:C18H20N4O2
MW:324.38
EINECS:
Product Categories:DACH&Trost Series;Chiral Nitrogen
Mol File:218290-24-5.mol
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) Structure
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) Chemical Properties
Melting point 170°C
alpha -95° (c 1, CH3OH)
Boiling point 663.4±50.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
pka12.51±0.40(Predicted)
color off-white
Optical Rotation[α]20/D -97.0°, c = 1 in methanol
InChI1S/C18H20N4O2/c23-17(15-9-3-5-11-19-15)21-13-7-1-2-8-14(13)22-18(24)16-10-4-6-12-20-16/h3-6,9-14H,1-2,7-8H2,(H,21,23)(H,22,24)/t13-,14-/m1/s1
InChIKeyBVYFDUZVVBXFBQ-ZIAGYGMSSA-N
SMILESO=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccn2)c3ccccn3
Safety Information
Risk Statements 36/37/38-22
Safety Statements 26-36/37/39-36/37
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) Usage And Synthesis
Reaction
  1. Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
  2. Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.
Reactions of 218290-24-5
UsesTrost Ligands for Asymmetric Allylic Alkylation
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) Preparation Products And Raw materials
Tag:(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)(218290-24-5) Related Product Information
1,2-CyclohexanediaMine, N,N,N'-triMethyl-, trans- Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine N,N'-Dimethyl-1,2-cyclohexanediamine N,N'-Bis-2-pyridylmethyl ethylenediamine 2-(Cyclohexylaminomethyl)pyridine (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) trans-N,N'-Diacetylcyclohexane-1,2-diamine (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)