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| Dibutoxymethane Basic information |
Product Name: | Dibutoxymethane | Synonyms: | 1,1’-[methylenebis(oxy)]bis-Butane;1-butoxymethoxy-butane;Butylal;Dibutoxymethane;Dibutyl formal;Di-n-butyl formal;Formaldehyde dibutyl acetal;formaldehydedibutylacetal | CAS: | 2568-90-3 | MF: | C9H20O2 | MW: | 160.25 | EINECS: | 219-909-0 | Product Categories: | | Mol File: | 2568-90-3.mol | |
| Dibutoxymethane Chemical Properties |
Melting point | -58.1°C | Boiling point | 180°C | density | 0,84 g/cm3 | vapor pressure | 1-1.11hPa at 22.7-25℃ | refractive index | n20/D1.406 | Fp | 60°C | form | clear liquid | color | Colorless to Almost colorless | Water Solubility | 222.5-250mg/L at 20℃ | LogP | 2.77-4.1 at 20-21.5℃ | EPA Substance Registry System | Butane, 1,1'-[methylenebis(oxy)]bis- (2568-90-3) |
Risk Statements | 36/37/38 | Safety Statements | 26-36/37/39 | RIDADR | 3271 | WGK Germany | 1 | HS Code | 2911.00.5000 | HazardClass | 3 | PackingGroup | III |
| Dibutoxymethane Usage And Synthesis |
Uses | Formaldehyde dibutyl acetal is a halogen-free and less toxic solvent that can be used to solubilize commercial low-density polyethylene (LDPE) samples to analyze molecular weight distribution using gel permeation chromatography (GPC). It can also be used as a reactant to prepare butoxymethyltriphenylphosphonium iodide, which is used for carbon homologation and also as a useful key intermediate in organic synthesis. | Preparation | A flask containing 15 gm (0.5 mole) of paraformaldehyde, 74 gm (1.0 mole) of η-butyl alcohol, and 2.0 gm of anhydrous ferric chloride is refluxed for 10 hr. The lower layer of 3-4 ml of material is discarded and then 50 ml of 10% aqueous sodium carbonate solution is added to remove the ferric chloride as ferric hydroxide. The product is shaken with a mixture of 40 ml of 20% hydrogen peroxide and 5 ml of 10% sodium carbonate solution at 45°C in order to remove any remaining aldehyde. The product is also washed with water, dried, and distilled from excess sodium metal to afford 62 gm (78%).
| Synthesis Reference(s) | The Journal of Organic Chemistry, 45, p. 3341, 1980 DOI: 10.1021/jo01304a039 | General Description | Formaldehyde dibutyl acetal is an acetal used in the manufacture of synthetic resins, antiseptics, deodorants, and fungicides. It is also used as a fuel additive to increase the octane number of gasoline or the n-cetane number of diesel fuels and reduce smoke and particulate emissions. |
| Dibutoxymethane Preparation Products And Raw materials |
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