4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE

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CAS:931-40-8
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CAS:931-40-8
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4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE Basic information
Product Name:4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE
Synonyms:GLYCEROL CARBONATE;GLYCEROL 1,2-CARBONATE;GLYCERYL CARBONATE;1-O,2-O-Carbonylglycerol;HYDROXYMETHYL DIOXOLANONE;4-methylol-1,3-dioxolan-2-one;4-Hydroxymethyl-1,3-dioxolan-2-one 4-Hydroxymethyl-2-oxo-1,3-dioxolane;4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE
CAS:931-40-8
MF:C4H6O4
MW:118.09
EINECS:213-235-0
Product Categories:Dioxanes & Dioxolanes;Dioxolanes;Carbonates;Carbonyl Compounds;Organic Building Blocks
Mol File:931-40-8.mol
4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE Structure
4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE Chemical Properties
Boiling point 137-140 °C/0.5 mmHg (lit.)
density 1.4 g/mL at 25 °C (lit.)
vapor pressure 0.93Pa at 25℃
refractive index n20/D 1.469(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Soluble in water
form Liquid
pka13.71±0.10(Predicted)
color Clear colorless to pale yellow
Water Solubility 1000g/L at 24℃
InChIInChI=1S/C4H6O4/c5-1-3-2-7-4(6)8-3/h3,5H,1-2H2
InChIKeyJFMGYULNQJPJCY-UHFFFAOYSA-N
SMILESO1CC(CO)OC1=O
LogP-1.39 at 25℃
EPA Substance Registry System1,3-Dioxolan-2-one, 4-(hydroxymethyl)- (931-40-8)
Safety Information
Safety Statements 23
WGK Germany 1
HS Code 29329990
MSDS Information
ProviderLanguage
SigmaAldrich English
4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE Usage And Synthesis
Uses4-(Hydroxymethyl)-1,3-dioxolan-2-one is used in method of finishing a metallic surface.
PreparationA stirred mixture of potassium hydrogen carbonate (10.0 g, 0.1 mol), 18-crown-6 (0.2 g, 0.76 mmol), and 1-chloro-2,3-epoxypropane (27.6 g, 0.3 mol) was heated at 80℃ for 36 h. After cooling and removal of the potassium salt by filtration, the organic layer was washed with water and 991 was distilled at 152–160℃/0.6–0.8 mmHg; yield 4.83 g (41%).
Flammability and ExplosibilityNon flammable
Tag:4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE(931-40-8) Related Product Information
Methyl glycolate Diethyl (hydroxymethyl)phosphonate Hydroxyethyl Cellulose (S)-(-)-4-(METHOXYMETHYL)-1,3-DIOXOLAN-2-ONE Davercin 4-HYDROXYMETHYL-1,3-DIOXOLAN-2-ONE Trityl olmesartan 1,4,6-Tri-O-acetyl-a-D-mannopyranose 2,3-Carbonate Hexanoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-2-hydroxy-5-methyl-, (3aS,4R,7R,8aS,9S,10aR,12aS,12bR,13S,13aS)-7,12a-bis(acetyloxy)-13-(benzoyloxy)-3a,4,7,8,8a,9,10,10a,12,12a,12b,13-dodecahyd ro-9-hydroxy-5,8a,14,14-tetramethyl-2,8-dioxo-6,13a-methano-13aH-oxeto[2'',3'':5',6']benzo[1',2':4,5]cyclodeca[1,2-d]-1,3-dioxol-4-yl ester, (2R,3S)- Methyl 2,3-O-Carbonyl-4,6-O-isopropylidene-a-D-mannopyranoside Methyl4,6-di-O-acetyl-2,3-carbonyl-b-D-mannopyranoside BroMo-4,6-di-O-acetyl-α-D-Mannopyranose-2,3-carbonate (R)-(+)-4-(METHOXYMETHYL)-1,3-DIOXOLAN-2-ONE 2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE 4-(1-PROPENYLOXYMETHYL)-1,3-DIOXOLAN-2-ONE 2,3-O-Carbonyl-4,6-O-isopropylidene-a-D-mannopyranoside ERYTHRITOL 1,2:3,4-DICARBONATE 1-Benzylglycerol-2,3-carbonate

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