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CALCIUM SULFIDE

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CALCIUM SULFIDE manufacturers

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CALCIUM SULFIDE Basic information
Product Name:CALCIUM SULFIDE
Synonyms:CALCIUM SULFIDE;Calcium sulfide (CaS);calciumsulfide(cas);Calcium-sulphide-;Calcium sulfide, #325 mesh, 99.9+% metals basis;Calcium sulfide, -325 mesh, pure, 99.9+%;CALCIUM SULFIDE, 99.99%;Calciumsulfide(99.9+%-Ca)
CAS:20548-54-3
MF:CaHS
MW:73.15
EINECS:243-873-5
Product Categories:metal chalcogenides;Inorganics;CalciumMaterials Science;Catalysis and Inorganic Chemistry;Chalcogenides;Chemical Synthesis;Metal and Ceramic Science
Mol File:20548-54-3.mol
CALCIUM SULFIDE Structure
CALCIUM SULFIDE Chemical Properties
Melting point 2000 °C
density 2.6
refractive index 2.12
solubility slightly soluble in H2O; insoluble in ethanol
form Powder
Specific Gravity2.5
color White
Water Solubility Slightly soluble in water. Insoluble in alcohol.
Sensitive Moisture Sensitive
Merck 14,1707
CAS DataBase Reference20548-54-3(CAS DataBase Reference)
EPA Substance Registry SystemCalcium sulfide (CaS) (20548-54-3)
Safety Information
Hazard Codes Xi,N
Risk Statements 31-36/37/38-50
Safety Statements 28-61
RIDADR UN 3179 4.1/PG 2
WGK Germany 2
TSCA Yes
HazardClass 4.3
PackingGroup III
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
CALCIUM SULFIDE Usage And Synthesis
Chemical PropertiesCALCIUM SULFIDE is OFF-WHITE POWDER
Physical propertiesCalcium sulfide is slightly soluble in water but insoluble in alcohol. It reacts with acids, producing hydrogen sulfide gas. Calcium sulfide is pale yellow to light gray with a bitter taste. It is hygroscopic, producing an odor of H2S in moist air.
OccurrenceCalcium sulfide occurs in nature as the mineral oldhamite. It has several applications. The ‘luminous’ calcium sulfide is used in phosphors, luminous paints and varnishes. Calcium sulfide also is used as an additive to lubri cants; and as a flotation agent in ore extraction.
UsesCALCIUM SULFIDE is used in electron emitters. Luminous CaS used for making luminous paints or varnishes.
UsesCalcium sulfide may be used to remove heavy metals from wastewater.
UsesCalcium sulfide is used in phosphors, lubricant additives and luminous paints. It reacts with elemental sulfur to give a lime-sulfur. Further, it is used in ore dressing and flotation agent. In addition to this, it is used as a depilatory in the tanning industry and in cosmetics.
PreparationCalcium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio:
Ca+S+heat→CaS
This white material crystallizes in a cubic structurelike rock salt and the bonding is highly ionic. This is consistent with its description as an ionic solid. CaS can also be produced by the “carbothermic reduction” of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to CO2:
CaSO4+ 2C→CaS+ 2CO2
This can react further:
3CaSO4+ CaS→4CaO+ 4SO2
Thus, this type of preparation cannot be used to prepare a pure CaS salt.
Calcium sulfide is available commercially as the pure sulfide as well as the polysulfide due to its extensive usage in the past as an insecticide both agriculturally and in home gardens.
General DescriptionCrystal structure of CaS is cubic. Electrical conductivity of calcium sufide in the temperature range of 650oC-1000oC was studied in great detail. It was concluded that CaS could be used as a potential electrolyte in a sulfur concentration cell.2
CALCIUM SULFIDE Preparation Products And Raw materials
Preparation Products3-Nitroaniline-->N1-(3-Aminophenyl)acetamide
Tag:CALCIUM SULFIDE(20548-54-3) Related Product Information
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