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| | Rhodiumtriphenylacetate Basic information |
| Product Name: | Rhodiumtriphenylacetate | | Synonyms: | Rhodiumtriphenylacetate;Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct;Dirhodium(II) Tetrakis(triphenylacetate) Dichloromethane Adduct;Rhodium(II) triphenylacetate dimer as complex with dichloromethane;Dirhodium(II) Tetrakis(triphenylacetate)
Rhodium(II) Bis(triphenylacetate) Dimer;DichloroMethane Adduct;Tetrakis(triphenylacetato)dirhodiuM(II) ;Rhodium(II)triphenylacetate dimer | | CAS: | 142214-04-8 | | MF: | C60H45O6Rh | | MW: | 964.9012 | | EINECS: | 200-838-9 | | Product Categories: | | | Mol File: | 142214-04-8.mol |  |
| | Rhodiumtriphenylacetate Chemical Properties |
| Melting point | 260-263°C | | storage temp. | Inert atmosphere,Room Temperature | | form | powder to crystal | | color | Green to Dark green | | InChI | InChI=1S/3C20H16O2.Rh/c3*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15H,(H,21,22);/q;;;+3/p-3 | | InChIKey | LJIVYHNRWSWCRU-UHFFFAOYSA-K | | SMILES | [Rh+3].C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 |
| Hazard Codes | Xn | | Risk Statements | 40 | | Safety Statements | 23-24/25-36/37 | | WGK Germany | 2 | | HS Code | 2931.90.6000 |
| | Rhodiumtriphenylacetate Usage And Synthesis |
| Uses | Catalyst for:
- Amination of allene carbamates
- Allene aziridination to stereoselectively prepare cyclic cabamates
- C-H bond nitrene insertion
- Enantioselective cyclopropanation
- Preparation of cyclic oxonium ylides
| | reaction suitability | core: rhodium
reagent type: catalyst
reaction type: C-H Activation |
| | Rhodiumtriphenylacetate Preparation Products And Raw materials |
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