2-アミノ-6-クロロトルエン(87-60-5)

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2-アミノ-6-クロロトルエン 製品概要
化学名:2-アミノ-6-クロロトルエン
英語化学名:3-Chloro-2-methylaniline
别名:2-Chloro-2-Methyl Aniline;3-Chloro-2-methylaniline, 98+%;3-Chlor-o-toluidin;3-chloro-2-toluidin;3-CHLORO-2-METHYLANILINE / 2-AMINO-6-CHLOROTOLUENE;3-chloro-o-toluidin;6-Chloro-2-amino-1-methylbenzene;6-chloro-ortho-toluidine
CAS番号:87-60-5
分子式:C7H8ClN
分子量:141.6
EINECS:201-756-6
カテゴリ情報:API intermediates;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:87-60-5.mol
2-アミノ-6-クロロトルエン
2-アミノ-6-クロロトルエン 物理性質
融点 2 °C (lit.)
沸点 115-117 °C/10 mmHg (lit.)
比重(密度) 1.185 g/mL at 25 °C (lit.)
屈折率 n20/D 1.588(lit.)
闪点 >230 °F
貯蔵温度 Store below +30°C.
溶解性4.5g/l
外見 Liquid
酸解離定数(Pka)pK1:2.49(+1) (25°C)
比重1.19
Clear yellow to red or red-brown
水溶解度 1g/L at 20℃
BRN 471697
InChIKeyZUVPLKVDZNDZCM-UHFFFAOYSA-N
LogP2.4
CAS データベース87-60-5(CAS DataBase Reference)
NISTの化学物質情報Benzenamine, 3-chloro-2-methyl-(87-60-5)
EPAの化学物質情報3-Chloro-2-methylaniline (87-60-5)
安全性情報
主な危険性 C,N,Xn
Rフレーズ 22-34-43-51/53-36/37/38
Sフレーズ 26-36/37/39-45-61-37/39
RIDADR UN 3429 6.1/PG 3
WGK Germany 2
RTECS 番号XU4760000
TSCA Yes
国連危険物分類 6.1
容器等級 III
HSコード 29214300
有毒物質データの87-60-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Fast Scarlet TR Base English
SigmaAldrich English
ACROS English
ALFA English
2-アミノ-6-クロロトルエン Usage And Synthesis
外観うすい黄色~暗褐色、液体
用途有機合成原料。
説明The chloromethylanilines are colorless orwhite crystalline solids or liquids, some have a mild fishyodor. Molecular weight (all isomers) =141.61. HazardIdentification (based on NFPA 704 M Rating System): (87-60-5) Health 2, Flammability 1, Reactivity 0. All are soluble in water and include:
化学的特性The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.
化学的特性clear yellow to red or red-brown liquid
使用3-Chloro-2-Methylaniline can be used for dyeing cotton, viscose, silk, nylon and acetate, as well as printing on cotton. It is mainly used for dyeing red, such as coupling with chromophenol AS, AS-BO, AS-ITR, etc.
使用Intermediate.
製造方法By 1-Methyl-2-nitrobenzene chlorination byproducts 3-Chloro-2-methylbenzenamine?reduction.
危険性Toxic by ingestion or inhalation.
安全性プロファイルPoison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also other chloro toluidine entries.
職業ばく露Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.
応急処置If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobinemia in urine.
貯蔵Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with chloromethylanilines you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area. Sources of ignition, such as smoking and openflames, are prohibited where Choromethyl anilines are handled, or stored in a manner that could create a potential fireor explosion hazard. A regulated, marked area should beestablished where this chemical is handled, used, or stored incompliance with OSHA Standard 1910.1045.
輸送方法Chlorotoluidines require a label of“POISONOUS/TOXIC MATERIALS.” They fall in DOTHazard Class 6.1 and Packing Group III.
不和合性Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.
Tags:87-60-5