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| 化学名: | 塩化白金(Ⅳ)酸アンモニウム | | 英語化学名: | Ammonium chloroplatinate | | 别名: | Ammoniumchloroplatinate(IV);ammoniumplatinicchloride;diammonium,(oc-6-11)-platinate(2-hexachloro-;diammoniumhexachloroplatinate(2-);Platinate(2-),hexachloro-, aMMoniuM (1:2), (OC-6-11)-;Ammonium hexachloroplatinate(IV) 99.999% trace metals basis;Ammonium hexachloroplatinate(Ⅳ);platinicammoniumchloride | | CAS番号: | 16919-58-7 | | 分子式: | Cl6Pt.2H4N | | 分子量: | 443.88 | | EINECS: | 240-973-0 | | カテゴリ情報: | chemical reaction,pharm,electronic,materials;halometallate salt;Inorganics | | Mol File: | 16919-58-7.mol |  |
| 融点 | °Cd ec.) | | 比重(密度) | 3.07 g/mL at 25 °C(lit.) | | 貯蔵温度 | under inert gas (nitrogen or Argon) at 2-8°C | | 溶解性 | insoluble in ethanol | | 外見 | Powder | | 色 | Yellow | | 比重 | 3.065 | | 水溶解度 | Slightly soluble in water. Insoluble in alcohol, ether and concentrated hydrochloric acid. | | Sensitive | Hygroscopic | | Merck | 14,548 | | 暴露限界値 | ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 | | 安定性： | hygroscopic | | CAS データベース | 16919-58-7(CAS DataBase Reference) | | EPAの化学物質情報 | Ammonium chloroplatinate (16919-58-7) |
| | 塩化白金(Ⅳ)酸アンモニウム Usage And Synthesis |
| 用途 | プラチナメッキ、スポンジ状白金の製造原料 | | 化学的特性 | YELLOW CUBIC CRYSTALS | | 化学的特性 | Ammonium chloroplatinate is an orange-red
crystalline cubic solid or yellow powder which decomposes
when heated. | | 使用 | Platinum plating; manufacture of spongy platinum. | | 使用 | Electroplating of platinum, manufacturing of platinum spongeAmmonium hexachloroplatinate(IV) is used in electroplating of platinum and to make spongy platinum. It reacts with copper(II) acetate and hydrogen sulfide to prepare Cu2PtIIPt3IVS8 which finds application in diamagnetic materials and semiconductors. It is also used in platinum plating. Further, it acts as an analytical reagent. | | 定義 | ChEBI: Ammonium hexachloroplatinate is an ammonium salt comprising separate ammonium cations and octahedral [PtCl6](2-) anions. It contains a hexachloroplatinate(2-). | | 燃焼性と爆発性 | Not classified | | 安全性プロファイル | Poison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of Cl-, NOx, and NH3. | | 職業ばく露 | It is used in photography, platinum
plating and in the manufacture of platinum sponge. | | 輸送方法 | UN3288 Toxic solids, inorganic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required. | | 不和合性 | This material is unstable and potentially
explosive. Incompatible with strong oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.); contact may cause fires
or explosions. Keep away from alkaline materials, strong
bases, strong acids, oxoacids, epoxides. | | 廃棄物の処理 | Because of the high value of
the metal, recovery is the economically indicated disposal
method. |
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