亜りん酸トリス(2,4-ジ-tert-ブチルフェニル)(31570-04-4)

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亜りん酸トリス(2,4-ジ-tert-ブチルフェニル) 製品概要
化学名:亜りん酸トリス(2,4-ジ-tert-ブチルフェニル)
英語化学名:Antioxidant 168
别名:Phenol,2,4-bis(1,1-dimethylethyl,phosphite;ANTIOXIDANT 168IRGANOX 168;Phenol,2,4-bis(1,1-dimethylethyl)-,phosphite(3:1;Tri(2,4-di-tert-butylphenyl)phosphite;Phenol,2,4-bis(1,1-dimethylethyl,phosphite(3:1);tri(2,4-Ditertrabutylphenyl)phosphiteester;Tris(2,4-di-tert-butylphenyl)phoshit;Doverphos-S-480
CAS番号:31570-04-4
分子式:C42H63O3P
分子量:646.94
EINECS:250-709-6
カテゴリ情報:Achiral Phosphine;Aryl Phosphine;Polymer Additives;Polymer Science;organophosphorus compound;Additives for Plastic;Polymer Additives;Polymer Science;Stabilizers;Organics
Mol File:31570-04-4.mol
亜りん酸トリス(2,4-ジ-tert-ブチルフェニル)
亜りん酸トリス(2,4-ジ-tert-ブチルフェニル) 物理性質
融点 181-184 °C(lit.)
沸点 594.2±50.0 °C(Predicted)
比重(密度) -0.98
闪点 46°C (115°F)
貯蔵温度 2-8°C
溶解性Acetonitrile (Slightly), Chloroform (Sparingly), Ethyl Acetate (Sparingly, Heate
外見 Powder
比重0.98
white
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sensitive moisture sensitive
安定性:Moisture Sensitive
InChIKeyJKIJEFPNVSHHEI-UHFFFAOYSA-N
LogP18 at 25℃
CAS データベース31570-04-4(CAS DataBase Reference)
EPAの化学物質情報Tris(2,4-di-tert-butylphenyl) phosphite (31570-04-4)
安全性情報
WGK Germany -
TSCA Yes
HSコード 2920900002
MSDS Information
ProviderLanguage
SigmaAldrich English
亜りん酸トリス(2,4-ジ-tert-ブチルフェニル) Usage And Synthesis
外観白色の結晶性粉末
溶解性トルエン及びヘキサンに溶けやすく、アセトンにやや溶けにくく、水及びメタノールにほとんど溶けない。
用途汎用の固体ホスファイト。ホスファイト系酸化防止剤の中でも特に耐加水分解性に優れる。
用途酸化防止剤定量用標準品。
説明ANTIOXIDANT 168 is a secondary antioxidant with excellent resistance to extraction by water, low volatility and high heat stability. It can effectively decompose hydroperoxides produced during the processing of polymeric materials. ANTIOXIDANT 168 usually not used alone, is compounded with hindered phenolic primary antioxidants such as 1010 to improve thermostability of polymer during the processing. There are over ten kinds of blends of 168 with phenolic antioxidants, widely use in the polymer materials such as PE, PP, PA, PC, ABS and so on.
使用This product is an excellent Antioxidant wnameely applied to polyethylene, polypropylene, polyoxymethylene, ABS resin, PS resin, PVC, engineering plastics, binding agent, rubber, petroleum etc. for product polymerization.
使用Tris(2,4-tert-butylphenyl) Phosphite is an intermediate in the synthesis of Tris(2,4-di-tert-butylphenyl)phosphate (T884500), a processing stabilizer for polymers.
主な応用Antioxidant 168 is a kind of phosphite ester antioxidant as processing stabilizer, used for polypropylene, polyethylene, and adhesives. The amount to be used may be 0.1%~1.0% depending on the substrate, processing conditions, and requirements of the end application. Blends with hindered phenols are particularly effective.In addition, they use combination with light stabilizers when need.
定義ChEBI: Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) is an alkylbenzene.
一般的な説明Tris(2,4-di-tert-butylphenyl) phosphite is a triaryl based phosphite that can be used in catalysis and metallation. Its characteristic to undergo metallation reaction and provide a cost effective synthetic processes allows it to be useful in biaryl coupling reactions.
燃焼性と爆発性Not classified
安全性Antioxidant 168 is approved for indirect food contact applications.
Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

WHITE INCOMPACT POWDER

CONTENT

99.0% min

MELTING RANGE

183-187 °C

VOLATILE

0.3% max

SOLUBILITY 2g/20ml TOLUENE

CLEAR

FREE 2,4-DITERT-BUTYPHENOL

0.2% max (wt)

TRANSMITTANCE

98% min 425nm

98% min 500nm

ACID VALUE,mg KOH/g

0.3% max

HYDROLYSIS TIME (90°C WATER

14 h min

SOLUBILITY

1% ACETONE

30% TOLUENE

36% CHLOROFORM

4% ETHYL ACETATE

11% n-HEXANE

0.1% ETHANOL

36% DICHLOROETHANE

6% max PHENYLETHYLENE

0.01% max WATER

Tags:31570-04-4