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ETHYL (DIPHENYLMETHYLSILYL)ACETATE

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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Suppliers list
Company Name: Sigma-Aldrich  
Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Products Intro: Product Name:2-Fluoro-6-iodobenzoic acid
CAS:13950-57-7
Purity:2-Fluoro-6-iodobenzoic acid Package:5ML Remarks:43125-5ML
Company Name: SIGMA-RBI  
Tel: 800 736 3690 (Orders)
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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Basic information
Product Name:ETHYL (DIPHENYLMETHYLSILYL)ACETATE
Synonyms:ethyl (methyldiphenylsilyl)acetate;2-(Methyldiphenylsilyl)acetic acid ethyl ester;ETHYL (DIPHENYLMETHYLSILYL)ACETATE
CAS:13950-57-7
MF:C17H20O2Si
MW:284.425
EINECS:
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Mol File:13950-57-7.mol
ETHYL (DIPHENYLMETHYLSILYL)ACETATE Structure
ETHYL (DIPHENYLMETHYLSILYL)ACETATE Chemical Properties
Safety Information
MSDS Information
ETHYL (DIPHENYLMETHYLSILYL)ACETATE Usage And Synthesis
Physical propertiesclear to light yellow liquids.
Usesvinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.
Preparationwhereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.
ETHYL (DIPHENYLMETHYLSILYL)ACETATE Preparation Products And Raw materials
Preparation Productsketene
Tag:ETHYL (DIPHENYLMETHYLSILYL)ACETATE(13950-57-7) Related Product Information
PHENYLTRIMETHYLSILANE ETHYL (DIPHENYLMETHYLSILYL)ACETATE (TRIMETHYLSILYL)ACETIC ACID DIMETHYLPHENYLSILYLACETIC ACID 2-(METHYLDIPHENYLSILYL)ETHANOL Diphenylsilane 2-(Trimethylsilyl)ethanol METHYL (TRIMETHYLSILYL)ACETATE DIMETHYLDIPHENYLSILANE Ethyl (trimethylsilyl)acetate