ジエチレン グリコール モノ-n-ブチル エーテル(112-34-5)

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ジエチレン グリコール モノ-n-ブチル エーテル 製品概要
化学名:ジエチレン グリコール モノ-n-ブチル エーテル
英語化学名:Diethylene glycol monobutyl ether
别名:Poly-Solv DB;poly-solvdb;BUTYLDIETHYLENEGLYCOL;Diethylenglycolmono-n-butylether;DIETHYLENE GLYCOL MONOBUTYL ETHER FOR DETERMINING THE CLOUD POINT OF NON-IONIC S;2-(2-buthoxyethoxy)ethanol;2-(2-butoxyethoxy)ethanol diethylene glycol monobutyl ether;Butoxyethoxy-Ethanol, 2-2-
CAS番号:112-34-5
分子式:C8H18O3
分子量:162.23
EINECS:203-961-6
カテゴリ情報:Colorless liquid with a mild pleasant odor. Mixes with water.;Alcohols;Building Blocks;C7 to C8;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols
Mol File:112-34-5.mol
ジエチレン グリコール モノ-n-ブチル エーテル
ジエチレン グリコール モノ-n-ブチル エーテル 物理性質
融点 -68 °C (lit.) -68 °C (lit.)
沸点 231 °C (lit.)
比重(密度) 0.967 g/mL at 25 °C (lit.)
蒸気密度5.6 (vs air)
蒸気圧30 mm Hg ( 130 °C)
屈折率 n20/D 1.432
闪点 212 °F
貯蔵温度 Store below +30°C.
溶解性soluble in Chloroform
外見 Liquid
酸解離定数(Pka)14.37±0.10(Predicted)
Clear Colorless
臭い (Odor)Mild, characteristic; pleasant.
酸塩基指示薬変色域(pH)7
爆発限界(explosive limit)0.7-5.9%(V)
水溶解度 soluble
Merck 14,1557
BRN 1739225
暴露限界値ACGIH: TWA 10 ppm
安定性:Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChIKeyOAYXUHPQHDHDDZ-UHFFFAOYSA-N
LogP1 at 20℃
CAS データベース112-34-5(CAS DataBase Reference)
NISTの化学物質情報2-(2-Butoxyethoxy)ethanol(112-34-5)
EPAの化学物質情報Diethylene glycol monobutyl ether (112-34-5)
安全性情報
主な危険性 Xi
Rフレーズ 36
Sフレーズ 24-26
WGK Germany 1
RTECS 番号KJ9100000
自然発火温度400 °F
TSCA Yes
HSコード 29094300
有毒物質データの112-34-5(Hazardous Substances Data)
毒性LD50 orally in rats, guinea pigs: 6.56, 2.00 g/kg (Smyth)
MSDS Information
ProviderLanguage
n-Butyl carbitol English
SigmaAldrich English
ACROS English
ジエチレン グリコール モノ-n-ブチル エーテル Usage And Synthesis
外観無色澄明の液体
定義本品は、次の化学式で表されるエーテルアルコールである。
溶解性水及びエタノールに極めて溶けやすい。
用途溶剤 (化学工業日報社)アクリロニトリル?ポリプロピレン?エチレンプロピレンゴム?オクタノール?プロピレンオキシド?アセトン?イソプロピルアルコールなどの原料 (化学工業日報社)
用途汎用溶剤。
化粧品の成分用途減粘剤、溶剤、香料
化学的特性Diethylene glycol monobutyl ether is a colorless, high-boiling liquid with a mild odour. It is miscible in proportions with water, alcohol (methanol), ketones (acetone), ethers (ethyl ether), aromatic hydrocarbons (benzene), paraffinic hydrocarbons (n-heptane), and halogenated hydrocarbons (carbon tetrachloride). As it is an ether-alcohol type compound it possesses solvent action for many substances such as oils, dyes, gums, and natural and synthetic resins. It is used as a high-boiling solvent in nitrocellulose lacquers and other synthetic coatings, baking lacquers, flash-dry printing inks, and dye bath.
使用Diethylene glycol monobutyl ether(DGBE) is widely used as a solvent for cellulose ester, lacquers, varnishes, cleaners, detergents, dyes, ink, and paint industries. it is also used as an intermediate for plasticizers and a diluent for hydraulic brake fluids, in addition to the production of piperonyl butoxy compounds. In France, its use in the cosmetics industry is permissible, wherein it is used as a solvent in hair dyes with a maximum concentration of 9%.
主な応用Diethylene glycol mono-n-butyl ether has a wide variety of applications in Chiral chemistry and green chemistry. It is also used in cosmetics. It is used as diluents and leveling agents in the manufacture of paints and in baking. It is also used in the manufacture of nitrocellulose. In brake fluid, it is used as an additive. It is used in the printing industry due to its slow evaporation rate. It is also used as a fixative for perfumes and antiseptics. It is used as an additive to prevent ice buildup in jet fuel.
製造方法Diethylene glycol monobutyl ether is prepared by co-heating ethylene oxide and ethylene glycol butyl ether under pressure.
一般的な説明Diethylene glycol monobutyl ether is a colorless liquid with a mild pleasant odor. Mixes with water. (USCG, 1999)
空気と水の反応Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Water soluble.
反応プロフィールButyldiglycol is a ether-alcohol derivative. The ether being relatively unreactive. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert alcohols to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.
健康ハザードDiethylene glycol monobutyl ether(DGBE) is an eye irritant. It showed low toxicity in test species.Toxic symptoms are similar to those ofother glycol ethers containing two etherealoxygen atoms. Inhalation for brief periods has no significant effect. Contact with liquid causes moderate irritation of eyes and corneal injury. Prolonged contact with skin causes only minor irritation. The high dosescaused pulmonary congestion. No renaldamage was reported. There is no reporton teratogenicity of this compound.
火災危険Butyldiglycol is combustible.
燃焼性と爆発性Non flammable
接触アレルゲンThis organic solvent belongs to the carbitols group and is included in waterbased liquids such as paints, surface cleaners, polishes, and disinfectants. It is considered to be an exceptional allergen.
安全性プロファイルModerately toxic by ingestion and intraperitoneal routes. Mddly toxic by skin contact. A severe eye irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, CO2, or dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.
純化方法Dry the ether with anhydrous K2CO3 or CaSO4, filter and fractionally distil it. Peroxides can be removed by refluxing with stannous chloride or a mixture of FeSO4 and KHSO4 (or, less completely, by filtration under slight pressure through a column of activated alumina). [Beilstein 1 IV 2394.]
廃棄物の処理DGBE is mixed with a combustible solventand burned in a chemical incinerator. Smallamounts may be disposed down the drainwith large amounts of water.
Tags:112-34-5