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| | (S)-(-)-〔(5,6),(5′,6′)-ビス(エチレンジオキシ)ビフェニル-2,2′-ジイル〕(ジフェニルホスフィン) 製品概要 |
| 化学名: | (S)-(-)-〔(5,6),(5′,6′)-ビス(エチレンジオキシ)ビフェニル-2,2′-ジイル〕(ジフェニルホスフィン) | | 英語化学名: | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN | | 别名: | (S)-SYNPHOS(R);(S)-SYNPHOS(TM);S-(-)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;(S)-(-)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE);(R)-SYNPHOS(R);(R)-SYNPHOS(TM);R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;(R)-(+)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE) | | CAS番号: | 503538-68-9 | | 分子式: | C40H32O4P2 | | 分子量: | 638.63 | | EINECS: | | | カテゴリ情報: | Chiral Phosphine;SYNPhos | | Mol File: | 503538-68-9.mol |  |
| | (S)-(-)-〔(5,6),(5′,6′)-ビス(エチレンジオキシ)ビフェニル-2,2′-ジイル〕(ジフェニルホスフィン) 物理性質 |
| 融点 | >260 °C | | 沸点 | 738.4±60.0 °C(Predicted) | | 貯蔵温度 | Inert atmosphere,Room Temperature | | 外見 | Powder | | 色 | white |
| Provider | Language |
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ACROS
| English |
| | (S)-(-)-〔(5,6),(5′,6′)-ビス(エチレンジオキシ)ビフェニル-2,2′-ジイル〕(ジフェニルホスフィン) Usage And Synthesis |
| 化学的特性 | White crystalline powder | | 反応性 |
- A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
- A ligand used for the dynamic kinetic resolution of α,β−unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
- Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
- Used in asymmetric Pauson-Khand reaction.
- Used in asymmetric iminonitroso Diels-Alder reaction.
- Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines
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