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| | 2-クロロ-2'-エチル-N-(2-メトキシ-1-メチルエチル)-6'-メチルアセトアニリド 製品概要 |
| | 2-クロロ-2'-エチル-N-(2-メトキシ-1-メチルエチル)-6'-メチルアセトアニリド 物理性質 |
| | 2-クロロ-2'-エチル-N-(2-メトキシ-1-メチルエチル)-6'-メチルアセトアニリド Usage And Synthesis |
| 外観 | 無色～黄褐色, 澄明の液体 | | 溶解性 | アセトンに溶ける。 | | 説明 | Metolachlor is a colorless or tan to brown,oily liquid with a slightly sweet odor. Molecularweight 5 283.83; Boiling point = 100℃ at 0.001 mmHg. Itis stable to about 300℃. Hazard Identification (based onNFPA-704 M Rating System): Health 1, Flammability 0,Reactivity 0. Slightly soluble in water. | | 化学的特性 | Pale Yellow Oil | | 化学的特性 | Metolachlor is a colorless or tan to brown, oily
liquid. Slightly sweet odor. | | 使用 | A selective pre-emergence herbicide. | | 使用 | Preemergence herbicide used to control most annual grasses and many annual weeds
in beans, chickpeas, corn, cotton, milo, okra, peanuts, peas, potatoes, safflower, soybeans
and some ornamentals. | | 定義 | ChEBI: 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide is an organochlorine compound that is 2-chloroacetamide substituted by a (2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl) group at the nitrogen atom. It is an aromatic amide, an ether, a member of benzenes and an organochlorine compound. | | 一般的な説明 | Tan to brown oily liquid with a slightly sweet odor. Slightly soluble in water and denser than water. Hence sinks in water. Soluble in most organic solvents. Used as a selective herbicide. | | 空気と水の反応 | Slightly soluble in water. Hydrolyzed by strong mineral acids and strong alkalis. | | 反応プロフィール | Metolachlor is a chlorinated acetamide. May react with azo and diazo compounds to generate toxic gases. May form flammable gases with strong reducing agents. Combustion generates mixed oxides of nitrogen (NOx). | | 健康ハザード | Can cause skin irritation and eye irritation. Headache and nausea may occur following prolong exposure. | | 农业用途 | Herbicide: Not approved for use in EU countries. Registered
for use in the U.S. Metolachlor is a selective herbicide that
is usually applied to crops before plants emerge from the
soil, and is used to control certain broadleaf and annual
grassy weeds in field corn, soybeans, peanuts, grain sorghum,
potatoes, pod crops, cotton, safflower, stone fruits,
nut trees, highway rights-of-way and woody ornamentals.
Prior to the RED of April, 1995, its primary use was on
corn, soybeans and sorghum. It inhibits protein synthesis;
thus, high-protein crops (e. g., soy) can be adversely
affected by excessive metolachlor application. Additives
may be included in product formulations to help protect
sensitive crops (i.e., sorghum) from injury. | | 製品名 | BICEP®[C]; BROADSTRIKE®; CGA-
24705®; CINCH®; CODAL®; COTORAN® MULTI®;
CYCLE®[C] DREXEL ME-TOO-LACHLOR®; DUAL®;
DUAL MAGNUM®; DUET®[C]; INTER PLUS®;
MEDAL®[C]; MILOCEP®; ONTRACK 8E®[C];
PENNANT®[C]; PRELUDE®[C]; PRIMAGRAM®;
PRIMEXTRA®; TURBO® | | 職業ばく露 | Metolachlor is a chlorinated acetamide
selective herbicide used for weed control in corn and for
controlling grasses in a variety of crops including cotton
and peanuts. | | 応急処置 | If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobin in urine. | | 環境運命予測 | Soil. Metolachlor and its degradation products combine with humic acids in soils and
small quantities are degraded to carbon dioxide (Ashton and Monaco, 1991). In soil, the
fungus Chaetomium globosum degraded metolachlor to 2-chloro-N-(2-ethyl-6-methylphenyl)
acetamide, 2-hydroxy-N-(2-methylvinylphenyl)-N-(methoxyprop-2-yl)acetamide, 3-
hydroxy-8-methyl-N-(methoxyprop-2-yl)-2-oxo-1,2,3,4-tetrahydraquinoline, 2-chloro-N-
(2-ethyl-6-methylphenyl)-N-(hydroxyprop-2-yl)acetamide and the tentatively identified
compounds 3-hydroxy-1-isopropyl-8-methyl-2-oxo-1,2,3,4-tetrahydroquinoline, N-(methoxyprop-
2-yl)-8-methyl-2-oxo-1,2,3,4-tetrahydroquinoline, N-(methoxyprop-2-yl)-N-(2-
methyl-6-vinyl)aniline and 1-(methoxyprop-2-yl)-7-methyl-2,3-dihydroindole (McGahen
8). Metolachlor was transformed by a strain of soil actinomycetes to the following products:
2-chloro-N-(2-ethyl-6-methylphenyl)-N-(hydroxyprop-2-yl)acetamide, 2-chloro-N-
2-(1-hydroxyethyl)-6-(methylphenyl)-N-(hydroxyprop-2-yl)acetamide, 2-chloro-N-(2-
ethyl-6-hydroxymethylphenyl)-N-(hydroxy-prop-2-yl)-acetamide, diastereoisomers of 2-
chloro-N-(2-ethyl-6-hydroxymethylphenyl)-N-(methoxyprop-2-yl)acetamide and 2-
chloro-N-2-(hydroxyethyl)-6-hydroxymethylphenyl)-N-(methoxyprop-2-yl)acetamide.
These products were formed via hydroxylation of both the N-alkyl and alkyl side chains
(Krause et al., 1985). In sterilized soil, metolachlor did not degrade after 4 months
(Bouchard et al., 1982).
Zimdahl and Clark (1982) reported half-lives of 15–38 and 33–100 days for the
herbicide in clay loam soil and sandy loam soil, respectively. They also reported that soil
moisture increased the dissipation rate. At 20°C, the dissipation rates of metolachlor in
the clay loam and sandy loam soils at 20, 50 and 80% soil moisture contents were 0.028,
0.053, 0.062 and 0.016, 0.028 and 0.037/day, respectively. The half-lives of metolachlor
in soil at maintained at temperatures of 30 and 40°C were approximately 3.85 and 2.75
weeks, respectively (Bravermann et al., 1986). The reported half-lives of metolachlor in
soil is approximately 6 days (Worthing and Hance, 1991) and 3–4 weeks (Bowman, 1988).
Groundwater. According to the U.S. EPA (1986) metolachlor has a high potential to
leach to groundwater.
Plant. Metabolizes in plants forming water soluble, polar, nonvolatile products (Hartley
and Kidd, 1987) and glutathione conjugates (Breaux et al., 1987).
Chemical/Physical. The volatilization half-life of metolachlor in an unstirred solution
was 20 days at 40°C. Volatilization is not significant at temperatures < 25°C (Lau et al.,
1995). | | 代謝経路 | A stable bacterial community absorbs and transforms
metolachlor from a liquid medium. From the medium
of the 7 day-old culture of the bacterial community, 2-
hydroxy-N-(2-methyl-6-vinylphenyl)-N-(2-methoxy-
methylethyl)acetamide and 4-(2-ethyl-6-methylphenyl)-
5-methyl-3-morpholinone are identified. The products
recovered from cells of J4-A include dechlorinated
metolachlor, a thiol compound, a more complicated
conjugate, and a non-sulfur-containing conjugate. By
sorghum microsomes, O-demethylation occurs in the
metolachlor degradation process. | | 貯蔵 | Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from oxidizers. Where possible, automatically pump liquid from drums or other storage containers to process containers | | 輸送方法 | UN2902 Pesticides, liquid, toxic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name
Required. UN3082 Environmentally hazardous substances,
liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous
hazardous material, Technical Name Required. | | 不和合性 | Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, nitrates. Compounds of
the carboxyl group react with all bases, both inorganic and
organic (i.e., amines) releasing substantial heat, water and a
salt that may be harmful. Incompatible with arsenic compounds
(releases hydrogen cyanide gas), diazo compounds,
dithiocarbamates, isocyanates, mercaptans, nitrides, and
sulfides (releasing heat, toxic, and possibly flammable
gases), thiosulfates and dithionites (releasing hydrogen
sulfate and oxides of sulfur). | | 廃棄物の処理 | In accordance with 40CFR
165 recommendations for the disposal of pesticides and
pesticide containers. Must be disposed properly by following
package label directions or by contacting your local or
federal environmental control agency, or by contacting
your regional EPA office. |
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