| | 1,3,5-トリニトロヘキサヒドロ-1,3,5-トリアジン 製品概要 |
| 化学名: | 1,3,5-トリニトロヘキサヒドロ-1,3,5-トリアジン | | 英語化学名: | HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE | | 别名: | HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE;HEXOGEN;1,3,5-TRINITRO-1,3,5-TRIAZACYCLOHEXANE;RDX;T4;TRIMETHYLENE TRINITRAMINE;RDX,1X1ML, ACN 1000UG/ML;SPHERICAL 1,3,5-TRINITRO-1,3,5-TRIAZACYCLOHEXANE | | CAS番号: | 121-82-4 | | 分子式: | C3H6N6O6 | | 分子量: | 222.12 | | EINECS: | 204-500-1 | | カテゴリ情報: | | | Mol File: | 121-82-4.mol |  |
| | 1,3,5-トリニトロヘキサヒドロ-1,3,5-トリアジン 物理性質 |
| 融点 | 205-206° | | 沸点 | 363.28°C (rough estimate) | | 比重(密度) | d420 1.82 | | 蒸気圧 | 0Pa at 20℃ | | 屈折率 | 1.6700 (estimate) | | 闪点 | 2℃ | | 貯蔵温度 | 2-8°C | | 酸解離定数(Pka) | -15.06±0.20(Predicted) | | 外見 | Colorless crystals | | 水溶解度 | 59.75mg/L(25 ºC) | | 暴露限界値 | TLV-TWA skin 1.5 mg/m3 (ACGIH and MSHA). | | 安定性： | Unstable. Explosive. | | LogP | 0.87 at 23℃ | | EPAの化学物質情報 | Cyclonite (121-82-4) |
| | 1,3,5-トリニトロヘキサヒドロ-1,3,5-トリアジン Usage And Synthesis |
| 解説 | RDX，ヘキソーゲン，シクロナイトなどとも呼ばれ，第2次大戦中に大量に用いられるようになった高性能爆薬。単独では雷管の添装薬に使われている。最も多い用途は，TNTとの2成分爆薬であるシクロトールやコンポジションBとして炸薬とされるものである。またコンポジションAやコンポジションCなどプラスチック結合爆薬やプラスチック爆薬の主成分としても用いられている。 無色の結晶で，融点204℃，結晶比重1.80，水に不溶，アルコール，ベンゼンなどには難溶，アセトンにはわずかに溶け，温フェノールおよび濃硝酸には易溶である。株式会社平凡社 世界大百科事典 第２版について 情報 | | 用途 | 高性能爆薬(主として軍事用、極少量が産業用) | | 説明 | Hexahydro-1,3,5-trinitro-s-triazine is a whitecrystalline compound; Boiling point=.260℃; Freezing/Melting point=203-204℃; Exothermicdecomposition=100℃; Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability(explosive), Reactivity (see incompatibilities). Insoluble inwater | | 化学的特性 | Hexahydro-1,3,5-trinitro-S-triazine is a
white crystalline compound. | | 使用 | High explosive; rodenticide.RDX is a convulsant. | | 使用 | Cyclonite is a high explosive and principal constituent of plastic bombs. It is preparedby treating hexamethylenetetramine with nitric acid,ammoniumnitrate,andaceticanhydride: It is also used as a rat poison. | | 定義 | Cyclonite: A highly explosive nitrocompound, (CH2N.NO2)3. It has acyclic structure with a six-memberedring of alternating CH2 groups andnitrogen atoms, with each nitrogenbeing attached to a NO2 group. It ismade by nitrating hexamine,C6H12N4, which is obtained from ammoniaand methanal. Cyclonite is avery powerful explosive used mainlyfor military purposes. It is also calledRDX. The abbreviation is for ‘ResearchDepartment composition X’,used at the Chemical Research andDevelopment Department, Woolwich. | | 定義 | ChEBI: An N-nitro compound that is 1,3,5-triazinane in which all three of the hydrogens attached to the nitrogens have been replaced by nitro groups. It is widely used in both industrial and military explosives. | | 一般的な説明 | Cyclotrimethylene trinitramine is an explosive. The explosion can be initiated by a sudden shock, high temperature or a combination of the two. The primary hazard is from blast effect and not from flying projectiles and fragments. Under prolonged exposure to heat or fire they can explode. | | 空気と水の反応 | Insoluble in water. | | 反応プロフィール | CYCLOTRIMETHYLENE TRINITRAMINE is incompatible with strong oxidizing agents, combustible materials and heat. Detonates on contact with mercury fulminate . Danger of explosion when dry. The self heating and explosive decomposition of the explosive and aqueous alkali (calcium hydroxide) has been studied, [Chem Abs., 1988, 109, 112968]. | | 健康ハザード | Cyclonite is a highly toxic substance. Repeated exposure can cause nausea, vomiting, and convulsions.
LD50 value, oral (rats): 100 mg/kg. | | 火災危険 | MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO. | | 安全性プロファイル | Poison by ingestion,
intraperitoneal, and intravenous routes. An
experimental teratogen. Other experimental
reproductive effects. A corrosive irritant to
skin, eyes, and mucous membranes. Cases of
epileptifonn convulsions have been reported
from exposure. It is one of the most
powerful high explosives in use today. Has
more shattering power than TNT and is
often mixed with TNT as a bursting charge
for aerial bombs, mines, and torpedoes. It is
easily initiated by mercury fulrmnate, which
may be used as a booster. When heated to
decomposition it emits toxic fumes of NOx.
See also MINES, NITRATES, and
EXPLOSIVES, HIGH. | | 職業ばく露 | A potential danger to those involved
in the manufacture of this material and its handling in
munitions and solid-propellant manufacture. It is also used
as a rat poison; a powerful military explosive; a base
charge for detonators; and in plastic explosives. | | 応急処置 | If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medcal attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit. | | 貯蔵 | Explosive. Color Code—Red Stripe: FlammabilityHazard: Store separately from all other flammable materals. Prior to working with this chemical you should betrained on its proper handling and storage. Detached storagein a secure area is recommended. Store in tightly closedcontainers in a cool well-ventilated area away from otherexplosives, combustibles, or strong oxidizers (such as chlorine, bromine, and fluorine). Also keep cyclonite away fromshock and heat sources. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical. Sources of ignition, such as smoking andopen flames, are prohibited where this chemical is used,handled, or stored in a manner that could create a potentialfire or explosion hazard. Wherever this chemical is used,handled, manufactured, or stored, use explosion-proof electrical equipment and fittings. | | 輸送方法 | UN0483 Cyclotrimethylenetrinitramine, desensi-
tized or Cyclonite, desensitized or Hexogen, desensitized or
RDX, desensitized, Hazard Class: 1D; Labels: 1D-
Explosive (with a mass explosion hazard); D-Substances or
articles which may mass detonate (with blast and/or frag-
ment hazard) when exposed to fire. UN0072
Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted
or Hexogen, wetted or RDX, wetted with not ,15% water
by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a
mass explosion hazard); D-Substances or articles which
may mass detonate (with blast and/or fragment hazard)
when exposed to fire. | | 純化方法 | RDX crystallises from acetone. [Bachmann & Sheehan J Am Chem Soc 71 1842 1949, Beilstein 26 II 5, 26 III/IV 22.] EXPLOSIVE. | | 不和合性 | Heat, physical damage, shock, and deto-
nators. Detonates on contact with mercury fulminate. Keep
away from other explosives, combustibles, oxidizers (such
as chlorates, nitrates, perchlorates, permanganates, perox-
ides; bromine, chlorine, and fluorine); reducing agents; and
aqueous alkaline solutions. | | 廃棄物の処理 | Pour over soda ash, neutralize
and flush to sewer with water. Also HMX may be recov-
ered from solid propellant waste. |
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