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4,4'-Dipyridyl N,N'-dioxide hydrate, 98% manufacturers
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| | 4,4'-Dipyridyl N,N'-dioxide hydrate, 98% Basic information |
| Product Name: | 4,4'-Dipyridyl N,N'-dioxide hydrate, 98% | | Synonyms: | 4,4'-Dipyridyl N,N'-dioxide hydrate 98%;4-(1-oxidopyridin-4-ylidene)pyridin-1-ium 1-oxide,hydrate;4,4'-Bipyridine] 1,1'-dioxide xhydrate;4,4′-Dipyridyl N,N′-dioxide hydrate;4,4'-Dipyridyl N,N'-dioxide hydrate, 98%;4,4'-Dipyridyl N,N'-dioxide hydrate 98% | | CAS: | 338950-86-0 | | MF: | C10H8N2O2.2H2O | | MW: | 224.215 | | EINECS: | | | Product Categories: | C9 to C46;Heterocyclic Building Blocks;Heterocyclic Compounds;Pyridines;Building Blocks;C10;Chemical Synthesis;Heterocyclic Building Blocks | | Mol File: | 338950-86-0.mol |  |
| | 4,4'-Dipyridyl N,N'-dioxide hydrate, 98% Chemical Properties |
| Melting point | 220 °C (dec.)(lit.) | | solubility | water: soluble25mg/mL, clear, yellow | | Water Solubility | water: soluble 25mg/mL, clear, yellow | | InChI | 1S/C10H8N2O2.H2O/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10;/h1-8H;1H2 | | InChIKey | WGMXNNUHJLHXQI-UHFFFAOYSA-N | | SMILES | O.[O-][n+]1ccc(cc1)-c2cc[n+]([O-])cc2 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | WGK 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 4,4'-Dipyridyl N,N'-dioxide hydrate, 98% Usage And Synthesis |
| Uses | 4,4′-Dipyridyl N,N′-dioxide may be used:
- as bidentate ligand in the preparation of co-ordination polymers of terbium(III)
- as ligand in the preparation of 2D CuII complex, with a stacked wavelike structure, and 3D materials, with CoII and NiII
- in the preparation of a Mg-based luminescent MIL-53 metal-organic framework (MOF)
| | General Description | 4,4′-Dipyridyl N,N′-dioxide reacts with various transition-metal salts in MeOH to afford a range of coordination polymers with 1-D chain and 2-D sheet architectures incorporating 36-hxl and 44-sql topologies. 4,4′-Dipyridyl N,N′-dioxide is reported to undergo hydrothermal reaction with d(10) metal ions (Cd2+ and Zn2+) to form three-dimensional grid-like coordination polymers. The electron density of the halogen-bonded complex of 4,4′-dipyridyl-N,N′-dioxide with 1,4-diiodotetrafluorobenzene at 90K has been studied by X-ray diffraction. |
| | 4,4'-Dipyridyl N,N'-dioxide hydrate, 98% Preparation Products And Raw materials |
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