フルオロアセトアミド(640-19-7)

フルオロアセトアミド 製品概要
化学名:フルオロアセトアミド
英語化学名:FLUOROACETAMIDE
别名:Fluorakil 100;FLUORAKIL 100(R);FLUORACETAMIDE;FLUOROACETAMIDE;FUSSOL(R);COMPOUND 1081(R);FLUOROACETAMIDE PESTANAL, 100 MG;FLUORACETAMID
CAS番号:640-19-7
分子式:C2H4FNO
分子量:77.06
EINECS:211-363-1
カテゴリ情報:Amides;Carbonyl Compounds;Organic Building Blocks
Mol File:640-19-7.mol
フルオロアセトアミド
フルオロアセトアミド 物理性質
融点 106-108 °C(lit.)
沸点 259.0±10.0 °C(Predicted)
比重(密度) 1.1170 (estimate)
溶解性DMSO (Soluble), Methanol (Slightly)
外見 Solid
酸解離定数(Pka)14.60±0.40(Predicted)
Off-White to Pale Beige
Merck 13,4193
BRN 1739054
安定性:Stable.
CAS データベース640-19-7(CAS DataBase Reference)
EPAの化学物質情報Fluoroacetamide (640-19-7)
安全性情報
主な危険性 T+,T,Xi
Rフレーズ 24-28
Sフレーズ 36/37-45
RIDADR UN 2811 6.1/PG 2
WGK Germany 2
RTECS 番号AC1225000
Hazard Note Highly Toxic/Irritant
国連危険物分類 6.1(a)
容器等級 I
HSコード 29241200
有毒物質データの640-19-7(Hazardous Substances Data)
毒性LD50 i.p. in mice: 85 mg/kg (Matsumura, O'Brien)
MSDS Information
ProviderLanguage
SigmaAldrich English
フルオロアセトアミド Usage And Synthesis
説明Fluoroacetamide is an odourless, tasteless, white, crystalline water soluble. It is a fluorinated amide and reacts with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Fluoroacetamide is used as a rodenticide and insecticide to control rabbits but is dangerous for other species of pests, farm livestock, and humans. Fluoroacetamide is a noncombustible substance itself and does not burn but may decompose upon heating to produce irritating, corrosive, and/or toxic fumes. On decomposition, fluoroacetamide releases nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, HF gas, and nitrogen gas.
化学的特性crystals
化学的特性Fluoroacetamide is a colorless, crystalline solid.
使用Rodenticide. Insecticide proposed mainly for use on fruits to combat scale insects, aphids, and mites.
定義ChEBI: Acetamide substituted at C-2 by a fluorine atom.
調製方法Fluoroacetamide is produced by reaction of α-chloroacetamide with potassium fluoride in tetrachloroethylene at elevated temperature.
一般的な説明Colorless crystalline powder. Used as a rodenticide. Highly toxic.
空気と水の反応Very soluble in water [Farm Chemicals]
反応プロフィールFLUOROACETAMIDE is a fluorinated amide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
危険性Extremely toxic; poison; mutagen.
健康ハザードFLUOROACETAMIDE is super toxic; probable oral lethal dose in humans is less than 5 mg/kg, or a taste (less than 7 drops) for a 150-lb. person. Chemically inhibits oxygen metabolism by cells with critical damage occurring to the heart, brain, and lungs resulting in heart failure, respiratory arrest, convulsions, and death.
火災危険Emits very toxic fumes of fluorine containing compounds and nitrogen oxides when heated to decomposition. Avoid decomposing heat.
安全性プロファイルA human poison by an unspecified route. Poison experimentally by ingestion, skin contact, intraperitoneal, subcutaneous, and intravenous routes. Human systemic effects by unspecified route: convulsions, coma, nausea and vomiting. Experimental reproductive effects. Mutation data reported. Used as an insecticide and rodenticide. When heated to decomposition it emits very toxic fumes of Fand NOx. See also FLUORIDES.
職業ばく露This material is an organofluorine rodenticide; insecticide proposed mainly for use on fruits to combat scale insects, aphids, and mites. Use is largely restricted to licensed pest control operators.
貯蔵Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area.
輸送方法UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
純化方法Crystallise fluoroacetamide from chloroform and dry it in a vacuum. [Beilstein 2 IV 454.]
不和合性Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
廃棄物の処理Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations govern ing storage, transportation, treatment, and waste disposal.
Tags:640-19-7