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| テトラブチルアンモニウムヘキサフルオロホスファート 製品概要 |
化学名: | テトラブチルアンモニウムヘキサフルオロホスファート | 英語化学名: | Tetrabutylammonium hexafluorophosphate | 别名: | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-);tetrabutylammonium-hexafluorphosophat;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE, ELECTROCHEM. GRADE;Tetrabutylammoniumhexafluorophosphate,98%;Tetrabutylammonium hexafluorophosphate 98%;N,N,N-tributyl-1-butanaminium tetrafluorophosphate;Tetra-n-butylammonium hexafluorophosphate ,99% | CAS番号: | 3109-63-5 | 分子式: | C16H36F6NP | 分子量: | 387.43 | EINECS: | 221-472-6 | カテゴリ情報: | metal fluorophosphate complex;Ammonium Polyhalides, etc. (Quaternary);Quaternary Ammonium Compounds;Ammonium SaltsAnalytical Reagents;Electrochemistry;Greener Alternatives: Catalysis;Phase Transfer Catalysts;Supporting Electrolytes for Electrochemistry;Ammonium Salts | Mol File: | 3109-63-5.mol | |
| テトラブチルアンモニウムヘキサフルオロホスファート 物理性質 |
融点 | 244-246 °C (lit.) | 沸点 | 242-246 °C | 貯蔵温度 | Inert atmosphere,Room Temperature | 溶解性 | acetonitrile: 0.1 g/mL, clear, colorless | 外見 | Crystalline Powder and/or Chunks | 色 | White to off-white | Sensitive | Hygroscopic | BRN | 4056584 | InChI | InChI=1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1 | InChIKey | BKBKEFQIOUYLBC-UHFFFAOYSA-N | SMILES | [N+](CCCC)(CCCC)(CCCC)CCCC.[P-](F)(F)(F)(F)(F)F | CAS データベース | 3109-63-5(CAS DataBase Reference) | NISTの化学物質情報 | Tetrabutylammonium hexafluorophosphate(3109-63-5) | EPAの化学物質情報 | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (3109-63-5) |
主な危険性 | Xi,Xn | Rフレーズ | 36/37/38-22 | Sフレーズ | 26-36/37 | RIDADR | 1759 | WGK Germany | 3 | Hazard Note | Irritant/Hygroscopic | TSCA | Yes | 国連危険物分類 | 8 | 容器等級 | III | HSコード | 29239000 |
| テトラブチルアンモニウムヘキサフルオロホスファート Usage And Synthesis |
外観 | 白色~うすい黄褐色、結晶性粉末~粉末 | 使用上の注意 | アルゴン封入 | 化学的特性 | off-white powder | 使用 | Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides. | 使用 | Tetrabutylammonium hexafluorophosphate (TBAPF6) or TBAHP can be used:
- As the supporting electrolyte in cyclic voltammetric studies.
- As a reactant in the synthesis of fluorescent nanofibrous sensing films for detecting nitro-explosive vapors.
| 一般的な説明 | Visit our Sensor Applications portal to learn more. | 純化方法 | Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.] |
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