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trans-Dibromobis(triphenylphosphine)-

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trans-Dibromobis(triphenylphosphine)- Basic information
Product Name:trans-Dibromobis(triphenylphosphine)-
Synonyms:TRANS-DIBROMOBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II),99%;Pd13.4%;trans-Dibromobis(triphenylphosphine)palladium(II), Pd;trans-Dibromobis(triphenylphosphine)palladium(II), Pd 13.4%;Dibromo bis(triphenylphosphine) palladium (II);trans-Bis(triphenylphosphine)palladium dibromide;Dibromopalladium - triphenylphosphine (1:2);triphenylphosphane dibromopalladium
CAS:22180-53-6
MF:C36H30Br2P2Pd
MW:790.798922
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium
Mol File:22180-53-6.mol
trans-Dibromobis(triphenylphosphine)- Structure
trans-Dibromobis(triphenylphosphine)- Chemical Properties
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in chloroform, toluene and benzene
form Powder
color yellow
Sensitive Hygroscopic
InChI1S/2C18H15P.2BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKeyMCSDDEAMPOYJJI-UHFFFAOYSA-L
SMILESBr[Pd]Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
Safety Information
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
trans-Dibromobis(triphenylphosphine)- Usage And Synthesis
Chemical Propertiesorange solid
UsesCatalyst for:
  • Equilibrium palladation of alkanes and arenes and functionalization of hydrocarbons

Reactant for:
  • Homocoupling reactions induced by P-C reductive elimination
  • Preparation of palladium imidazolylidene complexes via Suzuki coupling reactions
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
trans-Dibromobis(triphenylphosphine)- Preparation Products And Raw materials
Tag:trans-Dibromobis(triphenylphosphine)-(22180-53-6) Related Product Information
Dibromobis(tri-ortho-tolyphosphine)palladium(II) Diamminedinitritoplatinum(II) Dichlorotetraammine palladium trans-Dibromobis(triphenylphosphine)palladium(II) Triphenylphosphine