2-アミノ-4-ニトロフェノール(99-57-0)

2-アミノ-4-ニトロフェノール 製品概要
化学名:2-アミノ-4-ニトロフェノール
英語化学名:2-Amino-4-nitrophenol
别名:nci-c55958;p-nitroaminofenol;rodol42;2-AMINO-4-NITROPHENOL;2-Amino-4-nitrophenol;2-Hydroxy-5-nitroaniline; 3-Amino-4-hydroxynitrobenzene;3-AMINO-4-HYDROXYNITROBENZENE;P-NITRO-O-AMINOPHENOL;p-Nitro-o-aminophenol 4-Nitro-2-aminophenol
CAS番号:99-57-0
分子式:C6H6N2O3
分子量:154.12
EINECS:202-767-9
カテゴリ情報:dye intermediates;Amines;Aromatics;Intermediates & Fine Chemicals;Mutagenesis Research Chemicals;Pharmaceuticals;Aromatic Phenols;Phenoles and thiophenoles;Intermediates of Dyes and Pigments
Mol File:99-57-0.mol
2-アミノ-4-ニトロフェノール
2-アミノ-4-ニトロフェノール 物理性質
融点 140-143 °C (lit.)
沸点 322.46°C (rough estimate)
比重(密度) 1.3617 (estimate)
蒸気圧0.005Pa at 25℃
屈折率 1.6890 (rough estimate)
闪点 100 °C
貯蔵温度 Refrigerator, Under Inert Atmosphere
溶解性DMSO (Slightly), Methanol (Slightly)
酸解離定数(Pka)6.82±0.22(Predicted)
外見 Solid
Dark Yellow to Brown
水溶解度 slightly soluble
BRN 776533
LogP1.26
CAS データベース99-57-0(CAS DataBase Reference)
IARC3 (Vol. 57) 1993
EPAの化学物質情報2-Amino-4-nitrophenol (99-57-0)
安全性情報
主な危険性 Xi,Xn
Rフレーズ 36/37/38-68-43-40-20/21/22
Sフレーズ 26-45-36/37/39-36
RIDADR 2811
WGK Germany 2
RTECS 番号SJ6300000
Hazard Note Irritant
TSCA Yes
HSコード 29071990
有毒物質データの99-57-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
3-Amino-4-hydroxynitrobenzene English
SigmaAldrich English
ACROS English
ALFA English
2-アミノ-4-ニトロフェノール Usage And Synthesis
外観黄色~黄褐色, 結晶性粉末~粉末
溶解性エタノール及びアセトンに溶けやすく、水に溶けにくい。エタノール、エーテルに可溶。水に難溶。
用途有機合成原料、アゾ系染料の中間体。
化学的特性OCHRE CRYSTALLINE POWDER
使用2-Amino-4-nitrophenol is used in preparing some mordant dyes and in some hair dyes.
使用An aromatic constituent found in hair dyes and other cosmetic products with very low levels of mutagenic activity.
定義ChEBI: 2-Amino-4-nitrophenol is a member of 4-nitrophenols.
Synthesis Reference(s)Organic Syntheses, Coll. Vol. 3, p. 82, 1955
The Journal of Organic Chemistry, 45, p. 4992, 1980 DOI: 10.1021/jo01312a039
一般的な説明Orange prisms or yellow powder. No odor.
空気と水の反応Insoluble in water.
反応プロフィールOxidation of 2-Amino-4-nitrophenol may occur in the presence of air and violent decomposition may occur if 2-Amino-4-nitrophenol is allowed to dry out completely at elevated temperatures. 2-Amino-4-nitrophenol is stable when stored protected from light and under nitrogen for two weeks at temperatures up to 140° F, and storage under nitrogen for up to 24 weeks at room temperature (77° F) should produce no loss of stability. 2-Amino-4-nitrophenol is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. 2-Amino-4-nitrophenol is also incompatible with iron.
火災危険Flash point data for 2-Amino-4-nitrophenol are not available. 2-Amino-4-nitrophenol is probably combustible.
燃焼性と爆発性Non flammable
純化方法Crystallise the phenol from water. [Beilstein 13 IV 896.]
Tags:99-57-0