| 化学名: | ソジオチオベンゼン | | 英語化学名: | SODIUM THIOPHENOXIDE | | 别名: | BENZENETHIOL, SODIUM SALT, TECH., 90%;sodiumthiophenate;sodiumthiophenylate;Sodium benzenethiol salt;Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt;(Phenylthio) sodium;Phenylthiosodium;Sodiothiobenzene | | CAS番号: | 930-69-8 | | 分子式: | C6H7NaS | | 分子量: | 134.17 | | EINECS: | 213-224-0 | | カテゴリ情報: | | | Mol File: | 930-69-8.mol |  |
| 融点 | >300 °C (lit.) | | 溶解性 | DMSO (Slightly), Methanol (Slightly, Sonicated) | | 外見 | Powder | | 色 | Off-white to yellow to beige | | Hydrolytic Sensitivity | 0: forms stable aqueous solutions | | BRN | 3597302 | | 安定性： | Hygroscopic | | EPAの化学物質情報 | Benzenethiol, sodium salt (930-69-8) |
| | ソジオチオベンゼン Usage And Synthesis |
| 使用 | Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:
- As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
- Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
- Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
- Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.
| | 一般的な説明 | Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether. |
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