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トリス(2,4-ペンタンジオナト)鉄(III)(14024-18-1)

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トリス(2,4-ペンタンジオナト)鉄(III) 製品概要
化学名:トリス(2,4-ペンタンジオナト)鉄(III)
英語化学名:Ferric acetylacetonate
别名:Acetylacetone Iron(III) Salt Ferric(III) Acetylacetonate Iron(III) Acetylacetonate;TRIS(2,4-PENTANEDIONATO)IRON;TRIS(2,4-PENTANEDIONATO)IRON(3);TRIS(ACETYLACETONATO)IRON(III);(Acetylacetonato)iron(iii);(OC-6-11)-tris(2,4-pentanedionato-O,o’)-iron;4-pentanedionato-o,o’)-tris((oc-6-11)-iro;acetopefe(ii)
CAS番号:14024-18-1
分子式:C15H21FeO6
分子量:353.17
EINECS:237-853-5
カテゴリ情報:metal beta-diketonate complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Fe (Iron) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds;Organometallics;14024-18-1
Mol File:14024-18-1.mol
トリス(2,4-ペンタンジオナト)鉄(III)
トリス(2,4-ペンタンジオナト)鉄(III) 物理性質
融点 180-182 °C (dec.)(lit.)
沸点 110°C 2mm
比重(密度) 5.24 g/mL at 25 °C(lit.)
蒸気圧2.6 hPa (110 °C)
貯蔵温度 Store below +30°C.
溶解性Soluble in toluene.
外見 Powder
色Red
比重5.24
水溶解度 2 g/L (20 ºC)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 4157960
暴露限界値ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
安定性：Stable. Incompatible with strong bases, strong oxidizing agents.
LogP0.4 at 20℃
NISTの化学物質情報Iron tris(acetylacetonate)(14024-18-1)
EPAの化学物質情報Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1)
安全性情報
主な危険性 Xn
Rフレーズ 22-36
Sフレーズ 26-37/39
WGK Germany 3
RTECS 番号NO8960000
F 21
TSCA Yes
HSコード 29420000
毒性LD50 orally in Rabbit: 1872 mg/kg
MSDS Information
ProviderLanguage
Iron(III) acetylacetonate English
SigmaAldrich English
ACROS English
ALFA English
トリス(2,4-ペンタンジオナト)鉄(III) Usage And Synthesis
外観赤色～暗い赤色～褐色粉末～結晶
用途有機合成触媒。
用途有機元素分析用標準試料。
化学的特性dark red powder or Red-orange orthorhombic crystal, slightly soluble in water and heptane, easily soluble in ethanol, benzene, chloroform, acetone and ether. Solubility at 25°C: water 0.16, methanol 9.5, toluene 21.3, benzene 52.5.
使用Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
使用Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4
使用Chemical Synthesis of Monodisperse Magnetic Nanoparticles
製造方法Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.
一般的な説明This product has been enhanced for catalytic efficiency.
燃焼性と爆発性Not classified
純化方法When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.]
Tags:14024-18-1