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| | Dimethyl 2,6-Pyridinedicarboxylate Basic information |
| | Dimethyl 2,6-Pyridinedicarboxylate Chemical Properties |
| Melting point | 121-125 °C(lit.) | | Boiling point | 100 °C(Press: 0.005 Torr) | | density | 1.231±0.06 g/cm3(Predicted) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Chloroform | | form | Solid | | pka | -0.46±0.10(Predicted) | | color | Off-White | | Water Solubility | Soluble in water(14 g/L) (25°C). Soluble in chloroform. | | InChI | InChI=1S/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3 | | InChIKey | SNQQJEJPJMXYTR-UHFFFAOYSA-N | | SMILES | C1(C(OC)=O)=NC(C(OC)=O)=CC=C1 | | CAS DataBase Reference | 5453-67-8(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 37/38-41 | | Safety Statements | 26-39 | | WGK Germany | 3 | | HS Code | 29333990 |
| | Dimethyl 2,6-Pyridinedicarboxylate Usage And Synthesis |
| Chemical Properties | Off-White Solid | | Uses | Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:
- ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivatives
- N,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base
- 1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione
| | Application | Dimethyl 2,6-pyridinedicarboxylate could be used as a starting material to synthesize four pyridine-bridged bis pyrazole ligands by Claisen condensation[1]. These ligands could be further treated with UCl4 to yield the corresponding novel mononuclear uranium(IV) complexes [UIV(R′′′2L)(Cl)4].
| | General Description | The standard molar enthalpy of formation for dimethyl 2,6-pyridinedicarboxylate (dimethylpyridine-2,6-dicarboxylate) has been calculated from the standard molar enthalpy of combustion, which was measured by a static bomb calorimeter. | | storage | Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. | | References | [1] Korzekwa, Jana , et al. "Synthesis and characterization of uranium(IV) tetrachloro complexes in bis-pyrazolylpyridine ligand environments." Dalton Transactions (2017):10.1039.C7DT02947K. |
| | Dimethyl 2,6-Pyridinedicarboxylate Preparation Products And Raw materials |
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