- cyclopropanol
-
- $1.00 / 1KG
-
2019-07-06
- CAS:16545-68-9
- Min. Order: 1KG
- Purity: 96%
- Supply Ability: 500kg
|
| | cyclopropanol Basic information |
| Product Name: | cyclopropanol | | Synonyms: | cyclopropanol;(1α)-Cyclopropanol;Cyclopropane-1-ol;2-Cyclopropanol;Hydroxycyclopropane;16545-68-9, CFCD16545689;opropanoL;cyclopropyl alcohol | | CAS: | 16545-68-9 | | MF: | C3H6O | | MW: | 58.08 | | EINECS: | | | Product Categories: | | | Mol File: | 16545-68-9.mol |  |
| | cyclopropanol Chemical Properties |
| Melting point | 180℃ | | Boiling point | 101-102℃ (760 Torr) | | density | 9.9110 g/cm3 | | refractive index | 1.4129 (589.3 nm 20℃) | | storage temp. | 2-8°C | | pka | 15.31±0.20(Predicted) | | InChI | InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2 | | InChIKey | YOXHCYXIAVIFCZ-UHFFFAOYSA-N | | SMILES | C1(O)CC1 |
| | cyclopropanol Usage And Synthesis |
| Description | Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals. | | Uses | Cyclopropanol is a basic building block. | | Definition | ChEBI: Cyclopropanol is a cyclopropane in which a hydrogen atom is replaced by a hydroxy group. It is a member of cyclopropanes and an aliphatic alcohol. | | References | [1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208. |
| | cyclopropanol Preparation Products And Raw materials |
|