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ChemicalBook Optimization Suppliers |
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Alfa Aesar |
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400-6106006 |
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| 化学名: | 1,6-ヘプタジイン | | 英語化学名: | 1,6-HEPTADIYNE | | 别名: | 1,6-HEPTADIYNE 98%;1,6-Heptadiyne, 97+%;1,6-Heptadiyne (6CI, 8CI, 9CI);Heptane-1,6-diyne;1,6-Heptadiyne,98%;1,6-HEPTADIYNE;1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%;1,6-Heptadiyne> | | CAS番号: | 2396-63-6 | | 分子式: | C7H8 | | 分子量: | 92.14 | | EINECS: | 219-253-5 | | カテゴリ情報: | Industrial/Fine Chemicals;Acetylenes;Acetylenic Hydrocarbons;Alkynes;Organic Building Blocks;Terminal | | Mol File: | 2396-63-6.mol |  |
| 主な危険性 | F | | Rフレーズ | 11 | | Sフレーズ | 16-29-33 | | RIDADR | UN 3295 3/PG 2 | | WGK Germany | 2 | | RTECS 番号 | MI5600000 | | TSCA | Yes | | 国連危険物分類 | 3 | | 容器等級 | II | | HSコード | 29012990 | | 毒性 | dog,LD50,oral,3830mg/kg (3830mg/kg),GASTROINTESTINAL: NAUSEA OR VOMITINGLIVER: "HEPATITIS, FIBROUS (CIRRHOSIS, POST-NECROTIC SCARRING)"BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY),Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 19, Pg. 389, 1960. |
| | 1,6-ヘプタジイン Usage And Synthesis |
| 外観 | 無色～うすい黄色又は緑色、液体 | | 用途 | 有機合成原料。 | | 化学的特性 | clear yellow liquid | | 使用 | 1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. | | 一般的な説明 | Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. Cyclocopolymerization of 1,6-heptadiyne with dipropargyl ether under nitrogen atmosphere using KSCN, KBr and KI as initiators in N,N-dimethyl formamide has been studied. |
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