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| テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート 製品概要 |
化学名: | テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート | 英語化学名: | TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE | 别名: | tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%;tetrakis(acetonitrile)copper hexa-fluorophosph;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%;Copper(I) tetrakis(acetonitrile) hexafluorophosphate | CAS番号: | 64443-05-6 | 分子式: | C8H12CuF6N4P | 分子量: | 372.72 | EINECS: | | カテゴリ情報: | organometallic complex;Cu;Copper;Catalysis and Inorganic Chemistry;Chemical Synthesis | Mol File: | 64443-05-6.mol | |
| テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート 物理性質 |
融点 | 160 °C (dec.) (lit.) | 貯蔵温度 | Inert atmosphere,Store in freezer, under -20°C | 外見 | solid | 色 | white to light blue | Sensitive | air sensitive, moisture sensitive |
| テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート Usage And Synthesis |
外観 | 白色~ほとんど白色粉末~結晶 | 使用 | Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively. It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
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