テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート(64443-05-6)

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テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート 製品概要
化学名:テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート
英語化学名:TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
别名:tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%;tetrakis(acetonitrile)copper hexa-fluorophosph;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%;Copper(I) tetrakis(acetonitrile) hexafluorophosphate
CAS番号:64443-05-6
分子式:C8H12CuF6N4P
分子量:372.72
EINECS:
カテゴリ情報:organometallic complex;Cu;Copper;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:64443-05-6.mol
テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート
テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート 物理性質
融点 160 °C (dec.) (lit.)
貯蔵温度 Inert atmosphere,Store in freezer, under -20°C
外見 solid
white to light blue
Sensitive air sensitive, moisture sensitive
安全性情報
Rフレーズ 36/37/38
Sフレーズ 26-36/37/39
WGK Germany 3
HSコード 2926907090
MSDS Information
ProviderLanguage
SigmaAldrich English
テトラキス(アセトニトリル)銅(I)ヘキサフルオロホスファート Usage And Synthesis
外観白色~ほとんど白色粉末~結晶
使用Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

Tags:64443-05-6