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| | トランス-N-(6-クロロ-3-ピリジルメチル)-N'-シアノ-N-メチルアセトアミジン 製品概要 |
| 化学名: | トランス-N-(6-クロロ-3-ピリジルメチル)-N'-シアノ-N-メチルアセトアミジン | | 英語化学名: | Acetamiprid | | 别名: | Ethanimidamide, N-(6-chloro-3-pyridinyl)methyl-N-cyano-N-methyl-, (1E)-;acetamiprid (iso);(1E)-N-[(6-Chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide;Acetamiprid;ADA 06200;NFK 17;Piorun;Stonkat | | CAS番号: | 135410-20-7 | | 分子式: | C10H11ClN4 | | 分子量: | 222.67 | | EINECS: | 603-921-1 | | カテゴリ情報: | Agrochemical;Agro-Products;Aromatics;Heterocycles;135410-20-7 | | Mol File: | 135410-20-7.mol |  |
| | トランス-N-(6-クロロ-3-ピリジルメチル)-N'-シアノ-N-メチルアセトアミジン 物理性質 |
| 融点 | 101-103°C | | 沸点 | 352.4±52.0 °C(Predicted) | | 比重(密度) | 1.17 | | 蒸気圧 | <1 x 10-6 Pa (25 °C) | | 貯蔵温度 | Inert atmosphere,2-8°C | | 溶解性 | DMSO: Soluble; Methanol: Soluble | | 外見 | A solid | | 酸解離定数(Pka) | -0.44±0.10(Predicted) | | 水溶解度 | 4200 mg l-1 (25 °C) | | InChI | InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+ | | InChIKey | WCXDHFDTOYPNIE-RIYZIHGNSA-N | | SMILES | C(/N(CC1=CC=C(Cl)N=C1)C)(=N\C#N)\C | | CAS データベース | 135410-20-7(CAS DataBase Reference) | | NISTの化学物質情報 | Acetamipride(135410-20-7) | | EPAの化学物質情報 | Acetamiprid (135410-20-7) |
| | トランス-N-(6-クロロ-3-ピリジルメチル)-N'-シアノ-N-メチルアセトアミジン Usage And Synthesis |
| 農薬用途 | 殺虫剤 | | 化学的特性 | Pale Yellow Solid | | 使用 | A novel neonicotinid insecticide against Holotrichia consanguinea in sugarcane. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumb
lebee colonies grow poorly and produce fewer queens. | | 使用 | Acetamiprid is a systemic insecticide for soil and foliar application.
It is used to control Hemiptera, especially aphids, Thysanoptera and
Lepidoptera on a wide range of crops, especially vegetables, fruit and tea. | | 定義 | ChEBI: The (E)-stereoisomer of acetamiprid. | | 农业用途 | Insecticide: This class of pesticides are chemically related to nicotine and used on corn and soybean seeds and are used to control sucking and chewing insects, and soil insects including
aphids, beetles, fruit moth, leaf-hoppers and-miners, thrips,
whiteflies [83] . Also used to control fleas on domestic animals. | | 代謝経路 | Acetamiprid is relatively stable to hydrolysis and to photodegradation
by sunlight. It is rapidly degraded in soils to form 6-chloropyridinyldimethylamine
and 6-chloronicotinic acid. The main pathways
of metabolism in plants are N-demethylation and subsequent oxidation
affording 6-chloronicotinic acid and 6-chloropicolyl alcohol. Two N-cyanoamidines
were formed after application of acetamiprid to cabbage
leaves. No information is available on the fate of the insecticide in insects
or mammals. | | Degradation | Acetamiprid is stable in buffer solutions at pH 4, 5 and 7 and under
sunlight. It is degraded slowly at pH 9 (45 °C) (PM). In a study of its
hydrolysis acetamiprid was converted quantitatively to N-methyl-
(6-chloro-3-pyridyl)methylamine (2) in 0.5-1 N sodium hydroxide at
90-95°C in 2 hours (see Scheme 1). N-Demethyl-acetamiprid (3) was
converted to (6-chloro-3-pyridyl)methylamine(4) at the same rate and
under similar conditions (Tokieda et al., 1997). |
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