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(R)-MONOPHOS

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(R)-MONOPHOS manufacturers

  • (R)-MONOPHOS
  • (R)-MONOPHOS pictures
  • 2025-04-04
  • CAS:185449-80-3
  • Min. Order: 1KG
  • Purity: 98%
  • Supply Ability: 1ton
  • (R)-MONOPHOS
  • (R)-MONOPHOS pictures
  • $1.00
  • 2019-08-06
  • CAS:185449-80-3
  • Min. Order: 1KG
  • Purity: 98%
  • Supply Ability: 10KG
(R)-MONOPHOS Basic information
Product Name:(R)-MONOPHOS
Synonyms:3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(S)-MONOPHOS;(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN (S)-MONOPHOS;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (S)-MONOPHOS;(S)-(+)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE;(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE;(R)-MONOPHOS;(R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
CAS:185449-80-3
MF:C22H18NO2P
MW:359.36
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:185449-80-3.mol
(R)-MONOPHOS Structure
(R)-MONOPHOS Chemical Properties
Melting point 190 °C (dec.)
Boiling point 548.7±33.0 °C(Predicted)
alpha +587° (c 0.06, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
pka1.22±0.20(Predicted)
color white
Optical RotationConsistent with structure
Sensitive moisture sensitive
InChIInChI=1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3
InChIKeyQCHAVHXSBZARBO-UHFFFAOYSA-N
SMILESO1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1N(C)C)C=CC=C3
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 2929.90.5090
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-MONOPHOS Usage And Synthesis
Uses1. Asymmetric hydrogenation of ketones and β-keto esters.
2. Light-induced, enantioselective hydrogenation.
UsesDSM MonoPhos Family of Highly Efficient Privileged Ligands
(R)-MONOPHOS Preparation Products And Raw materials
Tag:(R)-MONOPHOS(185449-80-3) Related Product Information
(R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethane adduct 3,4-a']dinaphthalen-4-yl)dimethylamine (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]amine 8-Bromoadenosine-3',5'-cyclic monophosphate sodium salt hydrate CYTOSINEARABINOSIDE,CYTOSINEARAB.MONOPHOS.,CYT.ARAB.TRIPHOS.,SHEEPANTI- CYCLIC-ADENOSINE-5'-MONOPHOS-PHATE-AGAROSE DSM MONOPHOS? LIGAND KIT DSM MONOPHOS TM LIGAND KIT