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| | trans-1,4-ジクロロ-2-ブテン 製品概要 |
| 化学名: | trans-1,4-ジクロロ-2-ブテン | | 英語化学名: | trans-1,4-Dichloro-2-butene | | 别名: | 2-Butene,1,4-dichloro-,(E)-;4-dichloro-(e)-2-buten;4-dichloro-trans-2-buten;trans-1,4-Dichlor-2-buten;TRANS-1,4-DICHLORO-2-BUTENE, TECH., 85%;TRANS-1,4-DICHLORO-2-BUTENE 1X1ML MEOH 2 000UG/ML;TRANS-1,4-DICHLORO-2-BUTENE, 1000MG, NEA T;TRANS-1,4-DICHLORO-2-BUTENE, 100MG, NEAT | | CAS番号: | 110-57-6 | | 分子式: | C4H6Cl2 | | 分子量: | 125 | | EINECS: | 203-779-7 | | カテゴリ情報: | Environmental Standards;Neats;Separate Source Standards;Alkenyl;Halogenated Hydrocarbons;Organic Building Blocks;Alpha Sort;D;DAlphabetic;DIA - DIC;Volatiles/ Semivolatiles;API intermediates | | Mol File: | 110-57-6.mol |  |
| | trans-1,4-ジクロロ-2-ブテン 物理性質 |
| | trans-1,4-ジクロロ-2-ブテン Usage And Synthesis |
| 外観 | 無色～うすい黄色透明液体 | | 化学的特性 | The 1,4-dichloro-2-butenes are colorless
liquids. Some have a distinct odor. (cis-isomer) | | 化学的特性 | clear colorless to light yellow liquid | | 使用 | 1,4-Dichloro-2-butene is used in the synthesis of anthraquinones used in the asymmetric dihydroxylation of olefins. Also used to prepare arylcarboxamides used as novel dopamine receptor antagonists. | | 定義 | ChEBI: Trans-1,4-Dichlorobutene is an organochlorine compound. | | Synthesis Reference(s) | Journal of the American Chemical Society, 73, p. 2118, 1951 DOI: 10.1021/ja01149a061
The Journal of Organic Chemistry, 36, p. 2088, 1971 DOI: 10.1021/jo00814a013 | | 一般的な説明 | Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene. | | 空気と水の反応 | Insoluble in water. | | 反応プロフィール | trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998]. | | 健康ハザード | (Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs. | | 火災危険 | The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. | | 職業ばく露 | DC occurs as a by-product in chloroprene manufacture and may be used as a chemical
intermediate | | 輸送方法 | UN3384 Toxic by inhalation liquid, flammable, n.
o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor
concentration ≧to 10 LC50, Hazard class: 6.1; Labels:
6.1-Poisonous materials, 3-Flammable liquid, Technical Name
Required, Inhalation Hazard Zone B. UN2920 Corrosive
liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive
material, 3-Flammable liquid. The code “D” identifies proper
shipping names which are appropriate for
describing materials for domestic transportation but may be
inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either
domestic or international transportation is involved | | 不和合性 | Vapors may form explosive mixture
with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away
from alkaline materials, strong bases, strong acids, oxoacids,
and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other,
more dangerous materials; attacks some plastics. | | 廃棄物の処理 | High-temperature incineration
with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment, and waste disposal. |
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