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Postion:Product Catalog >Chemical Reagents>Organic reagents>Silane>tert-Butylchlorodiphenylsilane
tert-Butylchlorodiphenylsilane
  • tert-Butylchlorodiphenylsilane
  • tert-Butylchlorodiphenylsilane
  • tert-Butylchlorodiphenylsilane

tert-Butylchlorodiphenylsilane NEW

Price $20
Package 1g
Min. Order: 10g
Supply Ability: 2000kg
Update Time: 2024-04-28

Product Details

Product Name: tert-Butylchlorodiphenylsilane CAS No.: 58479-61-1
Min. Order: 10g Purity: 98%
Supply Ability: 2000kg Release date: 2024/04/28

tert-Butylchlorodiphenylsilane Chemical Properties
Boiling point 90 °C0.01 mm Hg(lit.)
density 1.057 g/mL at 25 °C(lit.)
refractive index n20/D 1.568(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility miscible in most organic solvents.
form Liquid
color Clear colorless to yellow or slightly brown
Specific Gravity1.074
Water Solubility reacts
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 644023
CAS DataBase Reference58479-61-1(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, chloro(1,1-dimethylethyl)diphenyl-(58479-61-1)
EPA Substance Registry SystemSilane, chloro(1,1-dimethylethyl)diphenyl- (58479-61-1)
tert-Butylchlorodiphenylsilane Usage And Synthesis
Chemical PropertiesTert-Butylchlorodiphenylsilane is a colorless to pale brown oily liquid with pungent odor, may be used as silylating agent for derivatization of alcohols, ketones, carboxylic acids, amines, amides and mercaptanes selectively into functional groups in different sterical environments.
Physical propertiescolorless liquid, bp 93–95°C/0.015 mmHg; n20 D 1.5680; d 1.057 g cm?3.
UsesSeveral newmethods have been developed for using the reagent to protect primary and secondary alcohols as their TBDPS ethers. In the presence of ammonium nitrate or ammonium perchlorate, reaction between TBDPS-Cl and a primary alcohol, such as benzyl alcohol, in DMF provided excellent yields of the corresponding silyl ethers in just 15 min (eq 1).19 When silver nitrate was used as promoter, the reactions gave inferior yields under otherwise identical conditions.Article illustration
When TBDPS-Cl is used to react with hemiacetals, it converts hemiacetals into ring-opened silyl ether carbonyl compounds, instead of mixed acetals.Presumably, the sizable TBDPS group presents too much steric hindrance for the formation of the corresponding mixed silyl acetals.
Usestert-Butyldiphenylchlorosilane acts as a silylating reagent used to protect alcohols and in the preparation of silyl ethers. It plays a major role as a raw material and a precursor in organic synthesis and pharmaceuticals. It is also used for the synthesis of interphenylene phenyloxazoles 

Packing &shipping&Payment

Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms)1 - 10000>10000
Est. Time(days)5To be negotiated

Article illustration

Article illustration





Company Profile Introduction

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  • Since: 2021-09-01
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