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Acetoacetanilide(102-01-2)

Acetoacetanilide(102-01-2)
Product IdentificationBack to Contents
【Product Name】

Acetoacetanilide
【Synonyms】

1-(Phenylcarbamoyl)-2-propanone
3-Oxo-N-phenylbutanamide
4-(Phenylamino)-2,4-butanedione
4H-1-Benzopyran-4-one, 7-[[2-O-(6-deoxy-a-L-mannopyranosyl)-b-D-glucopyranosyl]oxy]-2,3-dihydro-5-hydroxy-2-(4-hydroxyphenyl)-, (2S)-
7-[(2S,3R,4S,5S,6R)-4,5-Dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one
Butanamide, 3-oxo-N-phenyl-
Coupler 633
Naringenin 7b-neohesperidoside
Naringenin 7-neohesperidoside
Naringenin 7-rhamnoglucoside
Naringoside
N-Phenylacetoacetamide
【CAS】

102-01-2
【CAS】

10236-47-2
【Formula】

C10H11NO2
【Formula】

C27H32O14
【Molecular Weight】

177.2
【Molecular Weight】

580.54
【EINECS】

202-996-4
【EINECS】

233-566-4
【RTECS】

QN6340000
【RTECS】

AK4200000
【RTECS Class】

Drug
【RTECS Class】

Other
【Merck】

12,6512
【Merck】

13,59
【Beilstein/Gmelin】

102012
【Beilstein/Gmelin】

473419
【Beilstein Reference】

5-18-04-00528
【Beilstein Reference】

4-12-00-00955
Physical and Chemical PropertiesBack to Contents
【Appearance】

Beige solid. A bioflavanoid found in grapefruit, giving it its bitter flavor.
【Appearance】

White crystalline solid.
【Solubility in water】

Insoluble
【Solubility in water】

5 g/L
【Melting Point】

130 - 132
【Melting Point】

171
【Boiling Point】

129 (32 torr)
【Vapor Pressure】

.01
【Density】

1.26 g/cm3
【pKa/pKb】

10.68 (pKa)
【pKa/pKb】

7.17 (pKa)
【Usage】

Antioxidant, antifungal.
【Usage】

Manufacture of yellow dyes, such as hansa & benzidine yellows, in rubber compounding, in organic syntheses.
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

May cause eye irritation.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Storage】

Store in a cool, dry place. Keep container closed when not in use.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Ingestion】

Ingestion of large amounts may cause gastrointestinal irritation. The toxicological properties of this substance have not been fully investigated.
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【EC Risk Phrase】

R 20/21/22
【EC Safety Phrase】

S 22 24/25
【EC Safety Phrase】

S 26 36/37
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective gloves and clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

162
【Autoignition】

450
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Fire Potential】

This chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.