ChemicalBook >>Basic Red 9>>4,4'-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride(569-61-9)

4,4'-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride(569-61-9)

4,4'-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride(569-61-9)
Product IdentificationBack to Contents
【Product Name】

4,4'-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride
【Synonyms】

4,4',4''-Triaminotriphenylmethane hydrochloride
4-[(4-Aminophenyl)-(4-imino-1-cyclohexa-2,5-dienylidene)methyl]aniline hydrochloride
Basic parafuchsine
Calcozine magenta N
Fuchsine dr-001
p-Fuchsin
【CAS】

569-61-9
【Formula】

C19H18ClN3
【Molecular Weight】

323.83
【EINECS】

209-321-2
【RTECS】

CX9850100
【RTECS Class】

Tumorigen; Mutagen
【Beilstein/Gmelin】

4164603
【EC Index Number】

611-031-00-X
【EC Class】

Carcinogenic Category 2
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless to red crystals or green powder.
【Solubility in water】

Slightly soluble
【Melting Point】

268
【Partition Coefficient】

-.21
【Usage】

Dye for textiles (silks & acrylics), leather, & paper, component of magenta (fuchsin) dye, biological stain.
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause effects similar to those described for ingestion. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood.
【Skin】

May cause skin irritation. May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. If absorbed, may cause symptoms similar to those for ingestion.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause irritation of the digestive tract. May cause methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Exposure may cause anemia and other blood abnormalities.
【EC Risk Phrase】

R 45
【EC Safety Phrase】

S 53 45
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged exposure may cause anemia and methemoglobinemia, characterized by dizziness, drowsiness, headache, breath shortness, cyanosis, rapid heart rate and chocolate-brown colored blood. Chronic exposure can affect thyroid function. May cause pituitary gland abnormalities.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Aniline is incompatible with acetic anhydride, chlorosulfonic acid, hexachloromelamine, nitric acid, nitric acid + nitrogen tetroxide and sulfuric acid, nitrobenzene and glycerine, oleum, ozone, perchloric acid + formaldehyde, perchromates, performic acid, potassium peroxide, propiolactone (beta), silver perchlorate, sodium peroxide, sulfuric acid, trichloromelamine, oxidizing materials, acids, alkalies, anilinium chloride, benzenediazonium-2-carboxylate, boron trichloride, 1-chloro-2,3-epoxypropane, dibenzoyl peroxide, nitromethane, nitrous acid, and tetranitromethane.
【Stability】

Stable under normal shipping and handling conditions. However, may decompose if heated.
【Decomposition】

Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Transport InformationBack to Contents
【HS Code】

3204 13 00
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