Product Identification | Back to Contents | 【Product Name】
alpha-Methylnitrobenzene | 【Synonyms】
1-Methyl-2-nitrobenzene 2-Methylnitrobenzene 2-Nitrotoluene Methylnitrobenzene | 【CAS】
88-72-2 | 【Formula】
C7H7NO2 | 【Molecular Weight】
137.13999999999999 | 【EINECS】
201-853-3 | 【RTECS】
XT3150000 | 【RTECS Class】
Tumorigen; Mutagen; Reproductive Effector | 【Merck】
12,6748 | 【Beilstein/Gmelin】
1907580 | 【Beilstein Reference】
4-05-00-00845 | 【EC Index Number】
609-006-00-3 | 【EC Class】
Toxic; Danger of cumulative effects; Dangerous for the Environment |
Physical and Chemical Properties | Back to Contents | 【Appearance】
Yellow liquid with an almond-like odor. | 【Solubility in water】
0.7 g/L | 【Melting Point】
-4 - -3 | 【Boiling Point】
221.7 | 【Vapor Pressure】
0.29 (25 C) | 【Density】
1.163 g/cm3 (20 C) | 【Partition Coefficient】
2.3 | 【Heat Of Vaporization】
59.1 kJ/mol | 【Heat Of Combustion】
-3597 kJ/mol | 【Usage】
For production of toluidine, tolidine, fuchsine, and various synthetic dyes. | 【Vapor Density】
4.72 | 【Saturation Concentration】
0.01% (20 C) | 【Odor threshold】
0.05 mg/L | 【Refractive Index】
1.5450 (20 C) |
First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | 【Handling】
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. |
Hazards Identification | Back to Contents | 【Inhalation】
May be fatal if inhaled. Causes respiratory tract irritation. Aspiration may cause respiratory swelling and pneumonitis. | 【Skin】
Causes mild skin irritation. | 【Eyes】
Causes mild eye irritation. | 【Ingestion】
Aspiration hazard. May be harmful if swallowed. Causes digestive tract irritation. | 【Hazards】
Containers may explode when heated. | 【EC Risk Phrase】
R 23/24/25 33 51/53 | 【EC Safety Phrase】
S 28 37 45 61 | 【UN (DOT)】
1664 |
Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%. | 【Exposure limit(s)】
TLV (as TWA): 2 ppm; 11 mg/m3 (skin) (ACGIH 1991-1992). OSHA PEL: TWA 5 ppm (30 mg/m3) skin NIOSH REL: TWA 2 ppm (11 mg/m3) skin NIOSH IDLH: 200 ppm | 【Poison Class】
3 |
Fire Fighting Measures | Back to Contents | 【Flash Point】
106 | 【Autoignition】
420 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam. | 【Upper exp. limit】
8.8 | 【Lower exp. limit】
1.47 | 【Fire Potential】
Moderately flammable. Combustible. |
Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Provide ventilation. |
Stability and Reactivity | Back to Contents | 【Disposal Code】
9 | 【Incompatibilities】
Oxidizing agents | 【Stability】
Stable under normal temperatures and pressures. | 【Decomposition】
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen. | 【Combustion Products】
Toxic fumes may be generated. |
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Company Name: |
Alfa Aesar |
Tel: |
400-6106006 |
Fax: |
021-67582001/03/05 |
WebSite: |
http://chemicals.thermofisher.cn |
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