| Product Identification | Back to Contents | 【Product Name】
Trimethylsilyl triflate | 【Synonyms】
Methanesulfonic acid, trifluoro-, trimethylsilyl ester
TMS triflate
Trimethylsilanol trifluoromethanesulfonate
Trimethylsilyl trifluoromethanesulfonate
Trimethylsilyl trifluoromethylsulfonate | 【CAS】
27607-77-8 | 【Formula】
C4H9F3O3SSi | 【Molecular Weight】
222.26 | 【EINECS】
248-565-4 | 【Merck】
12,9849 | 【Beilstein/Gmelin】
1868911 | 【EC Class】
flammable |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear slightly yellow liquid. | 【Solubility in water】
Insoluble | 【Boiling Point】
77 | 【Density】
1.225 g/cm3 (20 C) | 【Usage】
Catalyst and silylating agent for organic syntheses. | 【Vapor Density】
7.7 | 【Refractive Index】
1.3630 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | 【Skin】
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | 【Eyes】
Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | 【Handling】
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Hazards Identification | Back to Contents | 【Ingestion】
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. | 【Inhalation】
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Vapors may cause dizziness or suffocation. | 【Skin】
Causes skin burns. | 【Eyes】
Causes eye burns. | 【Hazards】
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | 【EC Risk Phrase】
R 10 14 34 37 | 【EC Safety Phrase】
S 26 36/37 45 | 【UN (DOT)】
2924 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
38 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Reacts violently with water. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. | 【Fire Potential】
Flammable/combustible material. May be ignited by heat, sparks or flames. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. |
| Stability and Reactivity | Back to Contents | 【Stability】
Stable at room temperature in closed containers under normal storage and handling conditions. | 【Incompatibilities】
Strong oxidizing agents. | 【Decomposition】
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride, silicon oxide. | 【Combustion Products】
Fire will produce irritating, corrosive and/or toxic gases. |
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| Company Name: |
Time Chemical Co., Ltd. |
| Tel: |
0794-7183888 13155888520 |
| Fax: |
0794-5269668 |
| WebSite: |
http://www.groupchem.com |
| Company Name: |
SHANG FLUORO |
| Tel: |
021-021-65170832 15601903708 |
| Fax: |
|
| WebSite: |
http://www.shangfluoro.com |
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