ChemicalBook >>N,N,N',N'-Tetramethylethylenediamine>>TEMED(110-18-9)

TEMED(110-18-9)

TEMED(110-18-9)
Product IdentificationBack to Contents
【Product Name】

TEMED
【Synonyms】

bis-(Dimethylamino)ethane
N,N,N,N-Tetramethylethylenediamine
【CAS】

110-18-9
【Formula】

C6H16N2
【Molecular Weight】

116.21
【EINECS】

203-744-6
【RTECS】

KV7175000
【RTECS Class】

Primary Irritant
【Beilstein/Gmelin】

1732991
【Beilstein Reference】

4-04-00-01172
【EC Index Number】

612-103-00-3
【EC Class】

Highly flammable; Harmful; Corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid. Slight ammoniacal odor.
【Solubility in water】

Miscible
【Melting Point】

-64
【Boiling Point】

120
【Vapor Pressure】

10 (20 C)
【Density】

0.7765 g/cm3 (20 C)
【pKa/pKb】

5.14 (pKb)
【Partition Coefficient】

.3
【Heat Of Vaporization】

35.9 kJ/mol
【Usage】

Preparation of epoxy curing agents, polyurethane formation, corrosion inhibitor, textile finishing agents, intermediate for quaternary ammonium compounds.
【Vapor Density】

4
【Refractive Index】

1.4179 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】

Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause systemic effects. May cause burning sensation in the chest.
【Skin】

Causes skin burns. May cause cyanosis of the extremities. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Ingestion of large amounts may cause CNS depression. May cause systemic effects.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
【EC Risk Phrase】

R 11 20/22 34
【EC Safety Phrase】

S 16 26 36/37/39 45
【UN (DOT)】

2372
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

17
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam.
【Upper exp. limit】

9
【Lower exp. limit】

1
【Fire Potential】

HIGHLY FLAMMABLE.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Disposal Code】

5
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2372
【Hazard Class】

3
【Packing Group】

II
【HS Code】

2921 29 00
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