| Product Identification | Back to Contents | 【Product Name】
o-Bromoaniline | 【Synonyms】
2-Amino-1-bromobenzene
2-Bromoaniline
2-Bromobenzenamine
-Aminobromobenzene | 【CAS】
615-36-1 | 【Formula】
C6H6BrN | 【Molecular Weight】
172.03 | 【EINECS】
210-421-3 | 【Beilstein/Gmelin】
742062 | 【Beilstein Reference】
4-12-00-01487 | 【EC Class】
toxic, dangerous for the environment |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear yellow solid or liquid. | 【Solubility in water】
Insoluble | 【Melting Point】
27 - 31 | 【Boiling Point】
229 | 【Vapor Pressure】
0.08 (25 C) | 【Density】
1.86 g/cm3 | 【pKa/pKb】
11.46 (pKb) | 【Partition Coefficient】
2.19 | 【Heat Of Vaporization】
46.4 kJ/mol | 【Vapor Density】
5.9 | 【Refractive Index】
1.6113 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Handling and Storage | Back to Contents | 【Storage】
Store in a cool, dry place. | 【Handling】
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. |
| Hazards Identification | Back to Contents | 【Inhalation】
May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause liver and kidney damage. May cause respiratory tract irritation. May cause cardiac abnormalities. | 【Skin】
May cause skin irritation. | 【Eyes】
May cause eye irritation. | 【Ingestion】
May cause irritation of the digestive tract. May cause liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause central nervous system depression. | 【Hazards】
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | 【EC Risk Phrase】
R 20/21/22 33 | 【EC Safety Phrase】
S 28 36/37 | 【UN (DOT)】
2810 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed. |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
91 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. | 【Fire Potential】
Combustible material: may burn but does not ignite readily. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Incompatibilities】
Acids - acid chlorides - acid anhydrides - chloroformates - strong oxidizing agents. | 【Stability】
Stable under normal temperatures and pressures. | 【Decomposition】
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, nitrogen. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
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