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Triphenyl phosphite(101-02-0)

Triphenyl phosphite(101-02-0)
Product IdentificationBack to Contents
【Product Name】

Triphenyl phosphite
【Synonyms】

Advance TPP
Phenyl phosphite
Phosphorous acid, triphenyl ester
Triphenoxyphosphine
Tris(phenoxy)phosphine
【CAS】

101-02-0
【Formula】

C18H15O3P
【Molecular Weight】

310.29000000000002
【EINECS】

202-908-4
【RTECS】

TH1575000
【RTECS Class】

Primary Irritant
【Beilstein/Gmelin】

1079456
【Beilstein Reference】

4-06-00-00695
【EC Index Number】

015-105-00-7
【EC Class】

Irritant; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, pale yellow liquid with a clean, pleasant odor.
【Solubility in water】

Insoluble
【Melting Point】

22 - 25
【Boiling Point】

360
【Vapor Pressure】

4E-5 (25 C)
【Density】

1.304 g/cm3 (-82 C)
【Partition Coefficient】

7.23
【Heat Of Vaporization】

58.2 kJ/mol
【Usage】

Chemical intermediate, stabilizer systems for resins, metal scavenger, diluent for epoxy resins.
【Refractive Index】

1.5884 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation. Low hazard for usual industrial handling.
【Skin】

Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
【Eyes】

Causes eye burns.
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract. May inhibit cholinesterase activity, thereby producing nervous system effects.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 36/38 50/53
【EC Safety Phrase】

S 28 60 61
【UN (DOT)】

2811
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

A delayed peripheral neuropathy of the dying back or peripheral axonopathy variety predominates. Between 10 and 40 days after exposure, abrupt onset of flaccid paralysis is noted. This may be followed by lower extremity spasticity with clonus, hyperreflexia, hypertonus, and a peculiar spastic gait. In severe cases the full extent of paralysis may not be reached until after 2 to 3 months. Recovery is variable. Mortality is usually low and approximately 5% of victims may remain paralyzed. TOCP produced toxic effects on both male and female REPRODUCTIVE SYSTEMS when Long-Evans rats were given doses of 0 to 400 mg/kg by gavage prior to, and during breeding. Spermatotoxic effects, includes reduced motility, concentration, velocity, and abnormal morphology. Damage to ovarian and uterine tissue also 1999).
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

188
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

This chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

25
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, oxides of phosphorus, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2811
【Hazard Class】

6.1
【Packing Group】

I; II; III
【HS Code】

2920 90 85
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