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Triphenyl phosphite

Secondary antioxidants Physical and chemical properties Chemical properties Uses Production methods
Triphenyl phosphite
Triphenyl phosphite structure
CAS No.
101-02-0
Chemical Name:
Triphenyl phosphite
Synonyms
p36;TPO;P 36;EFED;jp360;(PhO)3P;P(OPh)3;westontpp;mellite310;adkstabtpp
CBNumber:
CB5296820
Molecular Formula:
C18H15O3P
Formula Weight:
310.28
MOL File:
101-02-0.mol

Triphenyl phosphite Properties

Melting point:
22-24 °C(lit.)
Boiling point:
360 °C(lit.)
Density 
1.184 g/mL at 25 °C(lit.)
vapor density 
10.7 (vs air)
vapor pressure 
5 mm Hg ( 205 °C)
refractive index 
n20/D 1.59(lit.)
Flash point:
425 °F
storage temp. 
-20°C
solubility 
methanol: 25 mg/mL, clear
form 
Liquid
color 
Clear colorless to pale yellow
PH
1 (200g/l, H2O, 20℃)
Water Solubility 
insoluble
Sensitive 
Air & Moisture Sensitive
BRN 
1079456
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
HVLLSGMXQDNUAL-UHFFFAOYSA-N
CAS DataBase Reference
101-02-0(CAS DataBase Reference)
NIST Chemistry Reference
Phosphorous acid, triphenyl ester(101-02-0)
EPA Substance Registry System
Phosphorous acid, triphenyl ester(101-02-0)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  Xn,N,Xi
Risk Statements  36/38-50/53
Safety Statements  28-60-61-28A-26
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  TH1575000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29209085
Hazardous Substances Data 101-02-0(Hazardous Substances Data)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

NFPA 704

Diamond Hazard Value Description
1
0
Health  
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

Triphenyl phosphite price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T84654 Triphenyl phosphite 97% 101-02-0 5g $47.3 2018-11-13 Buy
Sigma-Aldrich T84654 Triphenyl phosphite 97% 101-02-0 3kg $197 2018-11-13 Buy
TCI Chemical T0510 Triphenyl Phosphite >97.0%(GC) 101-02-0 25g $21 2018-11-22 Buy
TCI Chemical T0510 Triphenyl Phosphite >97.0%(GC) 101-02-0 500g $31 2018-11-22 Buy
Alfa Aesar A18662 Triphenyl phosphite, 97% 101-02-0 500g $32.2 2018-11-13 Buy

Triphenyl phosphite Chemical Properties,Uses,Production

Secondary antioxidants

Triphenyl phosphite is called for short TPP, it is also known as triphenoxytitanium phosphine, it is phosphite-based compound, it is a secondary antioxidant, it has light stabilizing effect, it is applicable to polyvinyl chloride, polypropylene, polystyrene, poly acetate, ABS resin, epoxy resin and the like. Triphenyl phosphite is widely used as polyvinyl chloride chelating agent, when the metal soap is used as stabilizer, coordinating with this product can reduce the harm of the metal chlorides, it can keep transparency of product and inhibit the change in color. Further triphenyl phosphate is also used as flame retardant plasticizer.
Phosphite phenyl diisooctyl can be obtained by the transesterification reaction of triphenyl phosphite and isooctanol in the presence of catalyst, phosphite phenyl diisooctyl can be used as secondary antioxidant. It has good resistance to discoloration, it can increase oxidation resistance and light stability. It has chelating action in PVC, low toxicity, it can be used in plastic medical devices.
In addition, this product in the presence of sodium methoxide can proceed the transesterification reaction with methanol to form trimethyl phosphite.
Triphenyl phosphite is as raw material, it can react with octanol in the solution of sodium methoxide, octyl diphenyl phosphite can be prepared.
The above information are collated by Xiaonan edit Chemicalbook (2016-12-03).

Physical and chemical properties

It is colorless or pale yellow oily liquid. It has slightly with phenol odor. Molecular weight is 310. Color (APHA) <50. Acid value is <0.5mgKOH/g. Phosphorus content is 10%. The relative density is 1. 180~1.186 (25°/ 15.5℃). Viscosity is 12 mPa•s (38℃), 4.5mPa•s (99℃). The freezing point is 19~24℃. Melting point is 22~25℃. Boiling point is 220℃ (1333Pa). Flash point (open cup) is 218.3℃, ignition point is 243℃. Refractive index is 1.5880 ~1.5900 (25℃). Solubility (g/100g solvent): methanol> 10, benzene> 10 acetone> 10, it is insoluble in water. Triphenyl phosphate has irritating to the skin, rat oral LD50 is 2800mg/kg body weight, it is used as polymer antioxidant and stabilizer, it has better synergy effect with many phenolic antioxidants. By effect of phosphorus trichloride and phenol can get triphenyl phosphite.

Chemical properties

It is colorless to pale yellow monoclinic crystal below room temperature. It is colorless light yellow transparent oily liquid at room temperature or higher, it has pungent odor. It is insoluble in water, soluble in organic solvents such as ethanol, ethyl ether, acetone, benzene and the like.

Uses

(1) Triphenyl phosphite is used as chelating agents, plastics antioxidant, alkyd resin and pesticide intermediate raw material.
(2) It is used for synthetic rubber and resin stabilizer, PVC antioxidant, alkyd resin and pesticide intermediate raw material.
(3) Triphenyl phosphite is used as secondary antioxidants, it has effect of light stability, it is suitable for polyvinyl chloride, polypropylene, polystyrene, polyester, ABS resin, and epoxy resin. (4) It is used as chelating agent in PVC products, it can enable products to maintain transparency, and suppresse color change. It can also be used for the production of trimethyl phosphite.
(5) Antioxidants, stabilizers TPPi is mainly applied to polyvinyl chloride, polyethylene, polypropylene, polystyrene, polyester, ABS resin, epoxy resin, synthetic rubber antioxidant stabilizer for PVC vinyl products as chelating agent, when the metal is as based stabilizer, coordinating with the product can reduce the harm of metal chloride
(6) Chelating agent. Plastic products antioxidant. The synthesis of alkyd resins and polyester resins.
(7) Chelating agent. Plastic products antioxidant. The synthesis of alkyd resins and polyester resins.
(8) Chelating agent, it is widely used in all kinds of PVC products, it can enable products to maintain its transparency and suppress color change, and it can increase the antioxidant and light and heat stability of the primary stabilizer. In addition, the product is also used for PE, PP, ABS, SBS and other products, and it can be used for pesticide intermediates. It can be used for synthetic alkyd resins and polyester materials and polyester resins.

Production methods

It can be obtained from phenol and phosphorus trichloride. Raw material consumption (kg/t) phenol (freezing point ≥40.4 ℃) 940 phosphorus trichloride (99%) 480

Chemical Properties

Water-white to pale-yellow solid or oily liquid; pleasant odor. Combustible.

Uses

Chemical intermediate, stabilizer systems for resins, metal scavenger, diluent for epoxy resins.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Organophosphates, such as Triphenyl phosphite, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Safety Profile

Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion. An experimental eye and severe human skin irritant. Combustible when exposed to heat or flame. To fight fire, use CO2, mist, dry chemical. When heated to decomposition it emits toxic fumes of POx. See also PHENOL.

Purification Methods

Its ethereal solution is washed succesively with aqueous 5% NaOH, distilled water and saturated aqueous NaCl, then dried with Na2SO4 and distilled under vacuum after evaporating the diethyl ether. [Walsh J Am Chem Soc 81 3023 1959, Verkade & Coskren in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973, Beilstein 6 IV 695.]

Triphenyl phosphite Preparation Products And Raw materials

Raw materials

Preparation Products


Triphenyl phosphite Suppliers

Global( 238)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Tianjin Zhongxin Chemtech Co., Ltd.
022-89880739
022-66880086 sales@tjzxchem.com CHINA 559 58
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19947 60
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32607 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1737 55
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6402 58
Qingdao Hongjin Trading Co., Ltd.
0532-83657313
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Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24095 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20201 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 4697 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19978 58

View Lastest Price from Triphenyl phosphite manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-21 Triphenyl phosphite
101-02-0
US $2.00 / kg 1kg 99% 1000kg career henan chemical co
2018-11-08 Triphenyl Phosphate(TPP) CAS: 101-02-0
101-02-0
US $1.00 / G 100G 99.9% 50000 tons Hebei Ruishun Trade Co.,Ltd

Triphenyl phosphite Spectrum


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