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3-Methylbenzoyl chloride(1711-06-4)

3-Methylbenzoyl chloride(1711-06-4)
Product IdentificationBack to Contents
【Product Name】

3-Methylbenzoyl chloride
【Synonyms】

m-Methylbenzoyl chloride
m-Toluyl chloride
Toluoyl chloride
【CAS】

1711-06-4
【Formula】

C8H7ClO
【Molecular Weight】

154.59
【EINECS】

216-976-8
【RTECS】

DM6644000
【RTECS Class】

Other
【Beilstein/Gmelin】

878419
【Beilstein Reference】

4-09-00-01716
Physical and Chemical PropertiesBack to Contents
【Appearance】

Liquid.
【Solubility in water】

Insoluble
【Melting Point】

-23
【Boiling Point】

220
【Vapor Pressure】

0.12 (25 C)
【Density】

1.172 g/cm3 (20 C)
【Partition Coefficient】

2.67
【Heat Of Vaporization】

45.7 kJ/mol
【Vapor Density】

5.33
【Refractive Index】

1.54918 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Handling】

Wash thoroughly after handling. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

Causes gastrointestinal tract burns.
【Inhalation】

Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1760
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

76
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1760
【Hazard Class】

8
【Packing Group】

I; II; III
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