ChemicalBook >>4-Chloroaniline>>4-Chlorobenzenamine(106-47-8)

4-Chlorobenzenamine(106-47-8)

4-Chlorobenzenamine(106-47-8)
Product IdentificationBack to Contents
【Product Name】

4-Chlorobenzenamine
【Synonyms】

4-Chloroaniline
p-Chloroaminobenzene
p-Chloroaniline
【CAS】

106-47-8
【Formula】

C6H6ClN
【Molecular Weight】

127.57
【EINECS】

203-401-0
【RTECS】

BX0700000
【RTECS Class】

Tumorigen; Mutagen; Primary Irritant
【Merck】

13,2136
【Beilstein/Gmelin】

471350
【Beilstein Reference】

4-12-00-01166
【EC Index Number】

612-137-00-9
【EC Class】

Carcinogenic Category 2; Toxic; Sensitising; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

White to pale yellow to tan colored, crystalline solid, slightly sweetish, characteristic amine odor.
【Solubility in water】

Slightly soluble
【Melting Point】

69 - 71
【Boiling Point】

232
【Vapor Pressure】

0.061 (25 C)
【Density】

1.43 g/cm3 (20 C)
【pKa/pKb】

10.03 (pKb)
【Partition Coefficient】

1.83
【Heat Of Vaporization】

79.0 kJ/mol
【Heat Of Combustion】

-7669 kJ/mol
【Usage】

Dye int, pharmaceuticals, agricultural chemicals.
【Vapor Density】

4.41
【Saturation Concentration】

20 ppm (0.002%) at 20 C (calculated)
【Refractive Index】

1.5546 (87 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale. Wash clothing before reuse.
Hazards IdentificationBack to Contents
【Inhalation】

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
【Skin】

Causes skin irritation. Harmful if absorbed through the skin. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
【Eyes】

Causes severe eye irritation.
【Ingestion】

Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Overexposure may cause methemoglobinemia.
【Hazards】

Containers may explode when heated.
【EC Risk Phrase】

R 45 23/24/25 43 50/53
【EC Safety Phrase】

S 53 45 60 61
【UN (DOT)】

2018
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause liver and kidney damage. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. May cause cancer according to animal studies. May cause reproductive and fetal effects.
Fire Fighting MeasuresBack to Contents
【Flash Point】

90
【Autoignition】

> 500
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Upper exp. limit】

8.8
【Lower exp. limit】

2.2
【Fire Potential】

Very flammable.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions.
Stability and ReactivityBack to Contents
【Disposal Code】

9
【Incompatibilities】

Acids, acid chlorides, acid anhydrides, chloroformates, and strong oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】

Irritating and toxic hydrogen chloride and oxides of nitrogen may form in fires.
Transport InformationBack to Contents
【UN Number】

2018
【Hazard Class】

6.1
【Packing Group】

II
【HS Code】

2921 42 10
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