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Benzyl benzoate(120-51-4)

Benzyl benzoate(120-51-4)
Product IdentificationBack to Contents
【Product Name】

Benzyl benzoate
【Synonyms】

Benzoic acid, phenylmethyl ester
Benzyl benzenecarboxylate
【CAS】

120-51-4
【Formula】

C14H12O2
【Molecular Weight】

212.25
【EINECS】

204-402-9
【RTECS】

DG4200000
【RTECS Class】

Agricultural Chemical and Pesticide; Drug; Natural Product
【Merck】

13,1129
【Beilstein/Gmelin】

2049280
【Beilstein Reference】

4-09-00-00307
【EC Index Number】

607-085-00-9
【EC Class】

Harmful
Physical and Chemical PropertiesBack to Contents
【Appearance】

Leaflets or oily liq. Faint pleasant aromatic odor.
【Solubility in water】

Insoluble
【Melting Point】

21
【Boiling Point】

323
【Vapor Pressure】

0.000229 (25 C)
【Density】

1.118 g/cm3
【Partition Coefficient】

3.97
【Heat Of Vaporization】

56.6 kJ/mol
【Heat Of Combustion】

-6690 kJ/mol
【Usage】

Camphor substitute in celluloid & plastic pyroxylin compound, pediculicide, acaricide.
【Vapor Density】

7.31
【Refractive Index】

1.5628 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use. Keep from contact with oxidizing materials.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation.
【Skin】

Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
【Eyes】

Causes eye irritation.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
【EC Risk Phrase】

R 22
【EC Safety Phrase】

S 25
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged or repeated skin contact may cause dermatitis.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

158
【Autoignition】

480
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out.
【Upper exp. limit】

4.5
【Lower exp. limit】

.7
【Fire Potential】

Slight fire hazard when exposed to heat or flame; can react with oxidizing materials.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents, acids, and bases.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Transport InformationBack to Contents
【HS Code】

2916 31 00
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