35019-66-0

(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine(35019-66-0)质谱(MS)

产品名称:(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine

CAS:35019-66-0

分子式:C12H17NO2

分子量: 207.27

¹HNMR

¹³CNMR

IR1

Mass

MS-NW-7612          
(4S,5S)-(+)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
C12H17NO2           (Mass of molecular ion:    207)

   Source Temperature: 240 °C
   Sample Temperature: 170 °C
   Reservoir, 75 eV

      15.0       1.7
      18.0       1.7
      27.0       1.1
      28.0       2.0
      29.0       1.2
      30.0       1.8
      39.0       2.1
      41.0       2.2
      42.0       6.9
      43.0     100.0
      44.0       4.4
      50.0       1.0
      51.0       2.6
      58.0       2.2
      59.0       1.5
      63.0       1.0
      65.0       1.5
      77.0       4.9
      78.0       1.1
      79.0       1.0
      83.0       1.4
      89.0       1.4
      90.0       1.9
      91.0       6.8
      92.0       1.5
     100.0       1.2
     101.0       3.9
     103.0       2.6
     104.0       1.4
     105.0       2.8
     106.0       1.4
     117.0       2.5
     118.0       3.9
     119.0       5.3
     120.0       1.9
     130.0       1.3
     131.0       1.0
     132.0       5.2
     133.0       1.2
     144.0       1.7
     149.0       1.1
     159.0       1.3
     192.0       1.2

90 MHz in CDCl3

¹H NMR	89.56 MHz
C₁₂ H₁₇ N O₂	0.05 ml : 0.5 ml CDCl₃
(4S,5S)-(+)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine

    Assign.     Shift(ppm)

      A          7.39 to 7.18
      B             5.061
      C     *1      4.238
      D     *1      3.871
      E             2.704
      F             1.520
      G             1.44
     
     J(B,E)=1.8HZ
     J(C,D)=-11.7HZ
     J(C,E)=1.8HZ
     J(D,E)=2.3HZ

     Hz     ppm     Int.

    662.00   7.392     31
    659.38   7.363     71
    657.56   7.343    116
    654.94   7.313    591
    648.13   7.237     35
    646.13   7.215     30
    646.00   7.214     30
    454.25   5.073     94
    452.44   5.052     92
    388.31   4.336     42
    386.00   4.310     44
    376.63   4.206     80
    374.31   4.180     78
    351.81   3.929     87
    350.00   3.908     88
    340.13   3.798     49
    338.31   3.778     49
    245.19   2.738     39
    243.31   2.717     86
    241.13   2.693     82
    239.19   2.671     37
    136.19   1.521   1000
    128.75   1.438    294

in CDCl3