Chemical Safety Data Sheet MSDS / SDS

2-(2-Butoxyethoxy)ethyl acetate

Revision Date:2023-11-29Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: 2-(2-Butoxyethoxy)ethyl acetate
  • CBnumber: CB6308191
  • CAS: 124-17-4
  • EINECS Number: 204-685-9
  • Synonyms: DBAC,Diethylene Glycol Monobutyl Ether Acetate

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordWarning
Precautionary statements
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
Hazard statements
H319 Causes serious eye irritation
H320 Causes eye irritation

SECTION 3: Composition/information on ingredients

Substance

  • Product name: 2-(2-Butoxyethoxy)ethyl acetate
  • Synonyms: DBAC,Diethylene Glycol Monobutyl Ether Acetate
  • CAS: 124-17-4
  • EC number: 204-685-9
  • MF: C10H20O4
  • MW: 204.26

SECTION 4: First aid measures

Description of first aid measures

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

NFPA 704

0
1
0
HEALTH 0 Poses no health hazard, no precautions necessary and would offer no hazard beyond that of ordinary combustible materials
FIRE 1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up

Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. Light sensitive. Heat sensitive.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment
Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 480 min

Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,2 mm Break through time: 40 min

Material tested:Dermatril? P (KCL 743 / Aldrich Z677388, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancelight yellow clear, liquid
  • Odourfruity
  • Odour ThresholdNo data available
  • pH3-4 (50g/l, H2O, 20℃)
  • Melting point/freezing pointMelting point/range: -31,99 °C at 1.013 hPa
  • Initial boiling point and boiling range245 °C - lit.
  • Flash point102 °C - closed cup
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsUpper explosion limit: 10,7 %(V) Lower explosion limit: 0,76 %(V)
  • Vapour pressureca.0,005 hPa at 20 °C
  • Vapour densityNo data available
  • Relative density0,978 g/cm3 at 25 °C
  • Water solubility65 g/l at 20 °C - soluble
  • Partition coefficient: n-octanol/waterlog Pow: 1,7 at 23 °C
  • Autoignition temperature265 °C at 1.013 hPa
  • Decomposition temperatureNo data available
  • Viscosity3,51 mm2/s at 20 °C -
  • Explosive propertiesNot explosiveIn use may form flammable/explosive vapour-air mixture.
  • Oxidizing propertiesNo data available

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

Heat Light.

Incompatible materials

Strong oxidizing agents, Strong bases

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - male - 11.920 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - 4 h - 72.500 mg/m3
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Other. Lungs, Thorax, or Respiration:Dyspnea. Lungs, Thorax, or Respiration:Other changes.
LD50 Dermal - Rabbit - 14.500 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 24 h (OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation - 18 - 24 h
Respiratory or skin sensitisation
- Guinea pig
Result: Does not cause skin sensitisation. (Buehler Test)
Germ cell mutagenicity
Ames test
Salmonella typhimurium Result: negative
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Toxicity
LD50 orally in Rabbit: 6500 mg/kg LD50 dermal Rabbit 5640 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish
static test LC50 - Pimephales promelas (fathead minnow) - 77 mg/l

- 96 h

Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - 664 mg/l - 48 h

Persistence and degradability

Biodegradability aerobic - Exposure time 20 d

Result: 73 % - Readily biodegradable. (OECD Test Guideline 301D)

Bioaccumulative potential

No bioaccumulation is to be expected (log Pow <= 4).

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Harmful to aquatic life. No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

SECTION 14: Transport information

SECTION 14: Transport information

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:
IATA:

UN number

ADR/RID: 1439 IMDG: 1439 IATA: 1439
ADR/RID: 1870 IMDG: 1870 IATA: 1870
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: - IMDG: - IATA: -
ADR/RID: 2574 IMDG: 2574 IATA: 2574
ADR/RID: 1224 IMDG: 1224 IATA: 1224
ADR/RID: 2321 IMDG: 2321 IATA: 2321
ADR/RID: - IMDG: - IATA: -
ADR/RID: - IMDG: - IATA: -
ADR/RID: 2811 IMDG: 2811 IATA: 2811
ADR/RID: - IMDG: - IATA: -

Packaging group

ADR/RID: - IMDG: - IATA: -
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (ACECLOFENAC) IMDG: TOXIC SOLID, ORGANIC, N.O.S. (ACECLOFENAC) IATA: Toxic solid, organic, n.o.s. (ACECLOFENAC)
ADR/RID: - IMDG: - IATA: -
ADR/RID: - IMDG: - IATA: -
ADR/RID: TRICHLOROBENZENES, LIQUID IMDG: TRICHLOROBENZENES, LIQUID IATA: Trichlorobenzenes, liquid
ADR/RID: KETONES, LIQUID, N.O.S. (Hexan-3-one) IMDG: KETONES, LIQUID, N.O.S. (Hexan-3-one) IATA: Ketones, liquid, n.o.s. (Hexan-3-one)
ADR/RID: TRICRESYL PHOSPHATE IMDG: TRICRESYL PHOSPHATE IATA: Tricresyl phosphate
ADR/RID: - IMDG: - IATA: -
ADR/RID: II IMDG: II IATA: II
ADR/RID: POTASSIUM BOROHYDRIDE IMDG: POTASSIUM BOROHYDRIDE IATA: Potassium borohydride Passenger Aircraft: Not permitted for transport
ADR/RID: AMMONIUM DICHROMATE IMDG: AMMONIUM DICHROMATE IATA: Ammonium dichromate

Transport hazard class(es)

ADR/RID: 5.1 IMDG: 5.1 IATA: 5.1
ADR/RID: 4.3 IMDG: 4.3 IATA: 4.3
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available
ADR/RID: III IMDG: III IATA: III
No data available
No data available
ADR/RID: III IMDG: III IATA: III
ADR/RID: II IMDG: II IATA: II
No data available
No data available
No data available
ADR/RID: I IMDG: I IATA: I
ADR/RID: II IMDG: II IATA: II

Environmental hazards

ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: no IMDG Marine pollutant: yes IATA: no

Special precautions for user

No data available
No data available
No data available
No data available
No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
EC Inventory:Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

See ICSC 0788.Check for peroxides prior to distillation; eliminate if found.
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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