Chemical Safety Data Sheet MSDS / SDS

4-Pyridinemethaneamine

Revision Date:2024-03-23Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: 4-Pyridinemethaneamine
  • CBnumber: CB6127561
  • CAS: 3731-53-1
  • EINECS Number: 223-092-6
  • Synonyms: 4-pyridinemethaneamine,4-(aminomethyl)pyridine

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
Hazard statements
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

SECTION 3: Composition/information on ingredients

Substance

  • Product name: 4-Pyridinemethaneamine
  • Synonyms: 4-pyridinemethaneamine,4-(aminomethyl)pyridine
  • CAS: 3731-53-1
  • EC number: 223-092-6
  • MF: C6H8N2
  • MW: 108.14

SECTION 4: First aid measures

Description of first aid measures

General advice
Consult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides, Nitrogen oxides (NOx)

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

NFPA 704

3
1
1
HEALTH 3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE 1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
REACT 1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Avoid inhalation of vapor or mist.

Normal measures for preventive fire protection. For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment
Eye/face protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancedark yellow clear, liquid
  • OdourNo data available
  • Odour ThresholdNo data available
  • pHNo data available
  • Melting point/freezing pointMelting point/range: -8 °C - lit.
  • Initial boiling point and boiling range230 °C - lit.
  • Flash point104 °C - closed cup
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsNo data available
  • Vapour pressure No data available
  • Vapour density No data available
  • Relative density1,065 g/cm3 at 25 °C
  • Water solubilityNo data available
  • Partition coefficient: n-octanol/waterNo data available
  • Autoignition temperatureNo data available
  • Decomposition temperatureNo data available
  • ViscosityNo data available
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong oxidizing agents, Strong acids

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx)

Other decomposition products - No data available In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Cough, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

SECTION 12: Ecological information

Toxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

SECTION 14: Transport information

SECTION 14: Transport information

IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:
IATA:

UN number

ADR/RID: 1987 IMDG: 1987 IATA: 1987
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
ADR/RID: 3272 IMDG: 3272 IATA: 3272
ADR/RID: - IMDG: - IATA: -
ADR/RID: 1170 IMDG: 1170 IATA: 1170
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
ADR/RID: 3077 IMDG: 3077 IATA: 3077
ADR/RID: 2834 IMDG: 2834 IATA: 2834
ADR/RID: 1989 IMDG: 1989 IATA: 1989
ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3)

Packaging group

ADR/RID: II IMDG: II IATA: II
ADR/RID: ALDEHYDES, N.O.S. (2,4,5-Trifluorobenzaldehyde) IMDG: ALDEHYDES, N.O.S. (2,4,5-Trifluorobenzaldehyde) IATA: Aldehydes, n.o.s. (2,4,5-Trifluorobenzaldehyde)
ADR/RID: PHOSPHOROUS ACID IMDG: PHOSPHOROUS ACID IATA: Phosphorous acid
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Diphenyl(2,4,6- trimethylbenzoyl)phosphine oxide) IATA: Environmentally hazardous substance, solid, n.o.s. trimethylbenzoyl)phosphine oxide)
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methyl 4-(3- formylphenyl)benzoate) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methyl 4-(3- IATA: Environmentally hazardous substance, solid, n.o.s. formylphenyl)benzoate)
ADR/RID: II IMDG: II IATA: II
ADR/RID: ETHANOL SOLUTION IMDG: ETHANOL SOLUTION IATA: Ethanol solution
ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods
ADR/RID: ESTERS, N.O.S. (Acetoxytrimethylsilane) IMDG: ESTERS, N.O.S. (Acetoxytrimethylsilane) IATA: Esters, n.o.s. (Acetoxytrimethylsilane)
ADR/RID: II IMDG: II IATA: II
ADR/RID: ALCOHOLS, N.O.S. (1,1,1-Trifluoropropan-2-ol) IMDG: ALCOHOLS, N.O.S. (1,1,1-Trifluoropropan-2-ol) IATA: Alcohols, n.o.s. (1,1,1-Trifluoropropan-2-ol)

Transport hazard class(es)

ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
(Methyl 4-(3- ADR/RID: 9 IMDG: 9 IATA: 9
(Diphenyl(2,4,6- ADR/RID: 9 IMDG: 9 IATA: 9
ADR/RID: 8 IMDG: 8 IATA: 8
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available
ADR/RID: III IMDG: III IATA: III
ADR/RID: III IMDG: III IATA: III
ADR/RID: III IMDG: III IATA: III
ADR/RID: III IMDG: III IATA: III
No data available
ADR/RID: II IMDG: II IATA: II
ADR/RID: II IMDG: II IATA: II
No data available
ADR/RID: II IMDG: II IATA: II

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes formylphenyl)benzoate) Special precautions for user Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available
No data available
Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
No data available
No data available
No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Vietnam National Chemical Inventory:Not Listed. website: https://chemicaldata.gov.vn/
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Not Listed. website: https://emb.gov.ph/
New Zealand Inventory of Chemicals (NZIoC):Not Listed. website: https://www.epa.govt.nz/
Korea Existing Chemicals List (KECL):Not Listed. website: http://ncis.nier.go.kr
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Not Listed. website: https://www.mee.gov.cn/
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
EC Inventory:Listed.

SECTION 16: Other information

Abbreviations and acronyms

  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • CAS: Chemical Abstracts Service
  • EC50: Effective Concentration 50%
  • IATA: International Air Transportation Association
  • IMDG: International Maritime Dangerous Goods
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • STEL: Short term exposure limit
  • TWA: Time Weighted Average

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

Recommended Products
4-(Ethylaminomethyl)pyridine SDS 3-(Aminomethyl)pyridine SDS 3-Aminopyridine SDS 4-Pyridinemethaneamine SDS 2-Dimethylaminopyridine SDS 2-Aminopyridine SDS Isonicotinamide SDS Pyridine SDS 2-Picolylamine SDS 4-Dimethylaminopyridine SDS