Chemical Safety Data Sheet MSDS / SDS

Acrylic acid

Revision Date:2023-11-29Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Acrylic acid
CBnumber: CB7307797
CAS: 79-10-7
EINECS Number: 201-177-9
Synonyms: acrylic acid,acrylate

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

Company Identification

Company: Chemicalbook
Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233 Keep container tightly closed.

P234 Keep only in original container.

P240 Ground/bond container and receiving equipment.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash hands thoroughly after handling.

P264 Wash skin thouroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P307+P311 IF exposed: call a POISON CENTER or doctor/physician.

P390 Absorb spillage to prevent material damage.

P391 Collect spillage. Hazardous to the aquatic environment

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Hazard statements

H226 Flammable liquid and vapour

H290 May be corrosive to metals

H302 Harmful if swallowed

H312 Harmful in contact with skin

H314 Causes severe skin burns and eye damage

H332 Harmful if inhaled

H335 May cause respiratory irritation

H370 Causes damage to organs

H371 May cause damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H400 Very toxic to aquatic life

SECTION 3: Composition/information on ingredients

Substance

Product name: Acrylic acid
Synonyms: acrylic acid,acrylate
CAS: 79-10-7
EC number: 201-177-9
MF: C3H4O2
MW: 72.06

SECTION 4: First aid measures

Description of first aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

In case of eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides

Flash back possible over considerable distance. Combustible.

Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures.

Development of hazardous combustion gases or vapours possible in the event of fire.

Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

HEALTH	3	Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE	2	Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur)
REACT	2	Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.

Environmental precautions

Do not let product enter drains. Risk of explosion.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb? ). Dispose of properly. Clean up affected area.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Hygroscopic.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: butyl-rubber

Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject? (KCL 898)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 120 min

Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

Exposure limits

TLV-TWA 10 ppm (30 mg/m³) (ACGIH).

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearancecolorless liquid
OdourNo data available
Odour ThresholdNo data available
pH2.1 (72.06g/l, H2O, 20℃)
Melting point/freezing pointMelting point/range: 13 °C - lit.
Initial boiling point and boiling range139 °C - lit.
Flash point48,5 °C - closed cup - DIN 51755 Part 1
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limits3.9-19.8%(V)
Vapour pressure 5,29 hPa at 25 °C
Vapour density 2.5 (vs air)
Relative density1,05 at 20 °C
Water solubility1.000 g/l at 25 °C
Partition coefficient: n-octanol/waterlog Pow: 0,46 at 25 °C - Bioaccumulation is not expected.
Autoignition temperature438 °C at 1.013 hPa
Decomposition temperatureNo data available
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: 1,15 mPa.s at 25 °C
Explosive propertiesNo data available
Oxidizing propertiesNo data available
λmax231nm(lit.)

Other safety information

Surface tension 69,6 mN/m at 1g/l at 20 °C

- Surface tension Dissociation constant 4,26 at 25 °C

SECTION 10: Stability and reactivity

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Reacts violently in contact with acids, amines, driers, polymerization accelerators and easily oxidized materials.

Polymerization can occur.

Conditions to avoid

Heating.

Incompatible materials

Copper, Nickel, Mild steel, Zinc

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

Acute toxicity estimate Oral - 500 mg/kg (Calculation method)
LD50 Oral - Rat - male - 1.000 - < 2.000 mg/kg (OECD Test Guideline 423)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.
Acute toxicity estimate Inhalation - 4 h - 11 mg/l (Calculation method)
LC50 Inhalation - Rat - 4 h - 3,6 mg/l
Remarks: (Lit.)(Regulation (EC) No 1272/2008, Annex VI)Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Acute toxicity estimate Dermal - 1.100 mg/kg (Calculation method)
LD50 Dermal - Rabbit - male - 1.000 mg/kg Remarks: (Regulation (EC) No 1272/2008, Annex VI)

Skin corrosion/irritation

Skin - Rabbit
Result: Causes severe burns.
(OECD Test Guideline 404)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)

Serious eye damage/eye irritation

Eyes - Rabbit
Result: Causes burns.
Remarks: (IUCLID)
Causes serious eye damage.

Respiratory or skin sensitization

Remarks:
(Lit.)

Germ cell mutagenicity

Test Type: Ames test
Test system: Salmonella typhimurium Result: negative
Remarks: (National Toxicology Program)
Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476
Result: negative
Test Type: unscheduled DNA synthesis assay Test system: rat hepatocytes
Metabolic activation: without metabolic activation Method: OECD Test Guideline 482
Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration. Species: Rat
Cell type: Bone marrow Application Route: Oral
Method: OECD Test Guideline 475 Result: negative
Test Type: dominant lethal test Species: Mouse
Cell type: Intrauterine Application Route: Oral
Result: negative Remarks: (ECHA)

Carcinogenicity

No data available

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Toxicity

LD50 orally in rats: 2.59 g/kg (Smyth)

SECTION 12: Ecological information

Toxicity

Toxicity to fish

flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 27 mg/l - 96 h

(US-EPA)

Toxicity to daphnia and other aquatic invertebrates

flow-through test EC50 - Daphnia magna (Water flea) - 95 mg/l - 48 h

(US-EPA)

Toxicity to algae

NOEC - Chlorella vulgaris (Fresh water algae) - 0,2 mg/l - 72 h (OECD Test Guideline 201)

Persistence and degradability

Biodegradability Result: 100 % - Readily eliminated from water

(OECD Test Guideline 302B)

Result: 81 % - Readily biodegradable. (OECD Test Guideline 301D)

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Biological effects:

Neutralise before sewage disposal.

Discharge into the environment must be avoided.

SECTION 13: Disposal considerations

Waste treatment methods

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration. 100 500 ppm potassium permanganate will degrade acrylic acid to a hydroxy acid which can be disposed of at a sewage treatment.

SECTION 14: Transport information

UN number

ADR/RID: 2218 IMDG: 2218 IATA: 2218

UN proper shipping name

	ADR/RID: ACRYLIC ACID, STABILIZED IMDG: ACRYLIC ACID, STABILIZED
IATA: Acrylic acid, stabilized
14.3	Transport hazard class(es) ADR/RID: 8 (3) IMDG: 8 (3)	IATA: 8 (3)
14.4	Packaging group ADR/RID: II IMDG: II	IATA: II
14.5	Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes	IATA: no
14.6	Special precautions for user No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

EC Inventory:Listed.

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

Acrylic acid is commercially available in stabilized form by addition of polymerization inhibitors (see Chemical Dangers).Acrylic acid solidifies below 14 °C leading to a localized depletion of stabilizer. Follow the manufacturer's instructions regarding thawing.An added stabilizer or inhibitor can influence the toxicological properties of this substance; consult an expert.Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.Someone who has shown signs of sensitivity to the substance should avoid any further contact with this substance or any other acrylates.

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.