Chemical Safety Data Sheet MSDS / SDS

Ethyl acrylate

Revision Date:2024-03-16Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Ethyl acrylate
CBnumber: CB8382425
CAS: 140-88-5
EINECS Number: 205-438-8
Synonyms: ethyl acrylate,CH2=CHCOOC2H5

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

Company Identification

Company: Chemicalbook
Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash hands thoroughly after handling.

P264 Wash skin thouroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P307+P311 IF exposed: call a POISON CENTER or doctor/physician.

P370+P378 In case of fire: Use … for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Hazard statements

H225 Highly Flammable liquid and vapour

H302 Harmful if swallowed

H311 Toxic in contact with skin

H314 Causes severe skin burns and eye damage

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H319 Causes serious eye irritation

H331 Toxic if inhaled

H332 Harmful if inhaled

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

H341 Suspected of causing genetic defects

H351 Suspected of causing cancer

H370 Causes damage to organs

H372 Causes damage to organs through prolonged or repeated exposure

H401 Toxic to aquatic life

H412 Harmful to aquatic life with long lasting effects

Disposal

WARNING.Cancer - https://oehha.ca.gov/proposition-65/chemicals/ethyl-acrylate

SECTION 3: Composition/information on ingredients

Substance

Product name: Ethyl acrylate
Synonyms: ethyl acrylate,CH2=CHCOOC2H5
CAS: 140-88-5
EC number: 205-438-8
MF: C5H8O2
MW: 100.12

SECTION 4: First aid measures

Description of first aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor

If inhaled

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

In case of eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Pay attention to flashback.

Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

HEALTH	3	Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE	3	Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
REACT	2	Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.

Environmental precautions

Do not let product enter drains. Risk of explosion.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.

Chemizorb?). Dispose of properly. Clean up affected area.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and

sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Storage stability

Recommended storage temperature 2 - 8 °C

Do not store under inert atmosphere. Polymerization can occur.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: butyl-rubber

Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject? (KCL 898)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 30 min

Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

Recommended Filter type: Filter A-(P2)

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

Exposure limits

TLV-TWA 5 ppm (～20 mg/m³) (ACGIH), 25 ppm (～100 mg/m³ (MSHA, NIOSH), TWA skin 25 ppm (100 mg/m³) (OSHA); IDLH 2000 ppm (NIOSH).

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearancecolorless liquid
Odourstingingpungent
Odour Threshold0.00026ppm
pHNo data available
Melting point/freezing pointMelting point/range: -71 °C - lit.
Initial boiling point and boiling range 99 °C - lit.
Flash point9 °C - closed cup
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limits Upper explosion limit: 12,1 %(V) Lower explosion limit: 1,8 %(V)
Vapour pressure 41,3 hPa at 20 °C
Vapour density 3,46 - (Air = 1.0)
Relative densityNo data available
Water solubility20 g/l at 20 °C
Partition coefficient: n-octanol/waterlog Pow: 1,18 at 25 °C - Bioaccumulation is not expected.
Autoignition temperature372 °C at 1.013,25 hPa
Decomposition temperatureNo data available
ViscosityViscosity, kinematic: 0,582 mm2/s at 25 °C Viscosity, dynamic: 0,535 mPa.s at 25 °C
Explosive propertiesNo data available
Oxidizing propertiesNo data available
Henry's Law Constant2.25(x 10^-3 atm?m³/mol) at 20 °C (approximate - calculated from water solubility and vapor pressure)

Other safety information

Relative vapor density

3,46 - (Air = 1.0)

SECTION 10: Stability and reactivity

Reactivity

Vapors may form explosive mixture with air.

Chemical stability

Hazardous polymerization may occur.

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Exothermic reaction with: chlorosulfonic acid

Risk of explosion with: polymerisation initiators Strong oxidizing agents Reducing agents Peroxides

Activated charcoal

Conditions to avoid

Heat. Oxygen free atmosphere.

May polymerize on exposure to light. Warming.

Incompatible materials

No data available

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

Acute toxicity estimate Oral - 1.120 mg/kg
(Calculation method)
LD50 Oral - Rat - male - 1.120 mg/kg Remarks: (ECHA)
Symptoms: Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract., Risk of aspiration upon vomiting., Pulmonary failure possible after aspiration of vomit.
Acute toxicity estimate Inhalation - 4 h - 9,14 mg/l (Calculation method)
LC50 Inhalation - Rat - male and female - 4 h - 9,137 mg/l (OECD Test Guideline 403)
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract, Inhalation may lead to the formation of oedemas in the respiratory tract.
Acute toxicity estimate Dermal - 1.800 mg/kg (Calculation method)
LD50 Dermal - Rabbit - 1.800 mg/kg Remarks: (IUCLID)

Skin corrosion/irritation

Skin - Rabbit
Result: Irritating to skin. (OECD Test Guideline 404)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Dermatitis

Serious eye damage/eye irritation

Eyes - Rabbit Result: Eye irritation Remarks: (IUCLID)
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)

Respiratory or skin sensitization

(OECD Test Guideline 429)
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)

Germ cell mutagenicity

Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Test Type: Micronucleus test Species: Mouse
Cell type: Bone marrow Application Route: Intraperitoneal Method: OECD Test Guideline 474 Result: negative

Carcinogenicity

No data available

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation. - Respiratory Tract
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
No data available

Aspiration hazard

No data available

Toxicity

LD50 orally in Rabbit: 550 mg/kg LD50 dermal Rabbit 1800 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish

semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 1,81 mg/l - 96 h

(OECD Test Guideline 203)

Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - 1,3 mg/l - 48 h (OECD Test Guideline 202)

Toxicity to algae

static test ErC50 - Desmodesmus subspicatus (green algae) - 5,28 mg/l - 72 h

(OECD Test Guideline 201)

Toxicity to bacteria

static test EC10 - activated sludge - > 100 mg/l - 72 h Remarks: (ECHA)

Persistence and degradability

Biodegradability aerobic - Exposure time 28 d

Result: 80 - 90 % - Readily biodegradable. (OECD Test Guideline 310)

Biochemical Oxygen Demand (BOD)

980 mg/g Remarks: (IUCLID)

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Additional ecological information

Discharge into the environment must be avoided.

SECTION 13: Disposal considerations

Waste treatment methods

Incompatibilities

Incompatible with oxidizers (may be violent), peroxides, polymerizers, strong alkalis; moisture, chlorosulfonic acid, strong acids; amines. May accumulate static electrical charges, and may cause ignition of its vapors.

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Waste Disposal

Incineration or by absorption and landfill disposal

SECTION 14: Transport information

UN number

ADR/RID: 1917 IMDG: 1917 IATA: 1917

UN proper shipping name

	ADR/RID: ETHYL ACRYLATE, STABILIZED IMDG: ETHYL ACRYLATE, STABILIZED
IATA: Ethyl acrylate, stabilized
14.3	Transport hazard class(es) ADR/RID: 3 IMDG: 3	IATA: 3
14.4	Packaging group ADR/RID: II IMDG: II	IATA: II
14.5	Environmental hazards ADR/RID: no IMDG Marine pollutant: no	IATA: no
14.6	Special precautions for user No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

EC Inventory:Listed.

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.Do NOT take working clothes home.

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.