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ChemicalBook >> CAS DataBase List >> Diethylzinc

Diethylzinc

Diethylzinc price.
  • $14 - $4116
  • Product name: Diethylzinc
  • CAS: 557-20-0
  • MF: C4H10Zn
  • MW: 123.51
  • EINECS:209-161-3
  • MDL Number:MFCD00009021
  • Synonyms:(C2H5)2Zn;ZINCDIETHYL;Zinc ethide;ZINC ETHYL;DIETHYLZINC, CYLINDER WITH 100 G;DIETHYLZINC SOLUTION, IN TOLUENE (1.1 M);DIETHYLZINC, 15 WT. % (1.1M) SOLUTION IN TOLUENE;DIETHYLZINC SOLUTION, ~1 M SOLUTION IN H EXANE
32 prices
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Brand
  • AHH
  • Alfa Aesar
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
  • Usbiological
Package
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  • 800g
  • 2l
  • ManufacturerAHH
  • Product numberMT-09298
  • Product descriptionDiethylzinc 98%
  • Packaging10g
  • Price$426
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044880
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes, packaged under Argon in resealable ChemSeal? bottles
  • Packaging25g
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number089038
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes
  • Packaging25g
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH37734
  • Product descriptionDiethylzinc, nominally 15% w/w in hexane packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging100ml
  • Price$102.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044880
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100g
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number089038
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes
  • Packaging100g
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number039564
  • Product descriptionDiethylzinc 96%
  • Packaging100g
  • Price$314
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH37734
  • Product descriptionDiethylzinc, nominally 15% w/w in hexane packaged under Nitrogen in resealable AcroSeal[t bottles
  • Packaging800ml
  • Price$364
  • Updated2024-03-01
  • Buy
  • ManufacturerOakwood
  • Product number098867
  • Product descriptionDiethylzinc solution 15 wt. % in toluene
  • Packaging1g
  • Price$14
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number098867
  • Product descriptionDiethylzinc solution 15 wt. % in toluene
  • Packaging5g
  • Price$18
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number098867
  • Product descriptionDiethylzinc solution 15 wt. % in toluene
  • Packaging25g
  • Price$35
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number098867
  • Product descriptionDiethylzinc solution 15 wt. % in toluene
  • Packaging50g
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number098867
  • Product descriptionDiethylzinc solution 15 wt. % in toluene
  • Packaging100g
  • Price$95
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number296112
  • Product descriptionDiethylzinc solution 1.0 M in hexanes
  • Packaging100ml
  • Price$138
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number406023
  • Product descriptionDiethylzinc solution 1.0 M in heptane
  • Packaging100ml
  • Price$159
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number256781
  • Product descriptionDiethylzinc ≥52 wt. % Zn basis
  • Packaging100g
  • Price$180
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-09298 Diethylzinc 98% 10g $426 2021-12-16 Buy
Alfa Aesar 044880 Diethylzinc, nominally 15% w/w in hexanes, packaged under Argon in resealable ChemSeal? bottles 25g $45 2021-12-16 Buy
Alfa Aesar 089038 Diethylzinc, nominally 15% w/w in hexanes 25g $45 2021-12-16 Buy
Alfa Aesar H37734 Diethylzinc, nominally 15% w/w in hexane packaged under Nitrogen in resealable AcroSeal[t bottles 100ml $102.65 2024-03-01 Buy
Alfa Aesar 044880 Diethylzinc, nominally 15% w/w in hexanes, packaged under Argon in resealable ChemSeal? bottles 100g $120 2021-12-16 Buy
Alfa Aesar 089038 Diethylzinc, nominally 15% w/w in hexanes 100g $120 2021-12-16 Buy
Alfa Aesar 039564 Diethylzinc 96% 100g $314 2024-03-01 Buy
Alfa Aesar H37734 Diethylzinc, nominally 15% w/w in hexane packaged under Nitrogen in resealable AcroSeal[t bottles 800ml $364 2024-03-01 Buy
Oakwood 098867 Diethylzinc solution 15 wt. % in toluene 1g $14 2021-12-16 Buy
Oakwood 098867 Diethylzinc solution 15 wt. % in toluene 5g $18 2021-12-16 Buy
Oakwood 098867 Diethylzinc solution 15 wt. % in toluene 25g $35 2021-12-16 Buy
Oakwood 098867 Diethylzinc solution 15 wt. % in toluene 50g $60 2021-12-16 Buy
Oakwood 098867 Diethylzinc solution 15 wt. % in toluene 100g $95 2021-12-16 Buy
Sigma-Aldrich 296112 Diethylzinc solution 1.0 M in hexanes 100ml $138 2024-03-01 Buy
Sigma-Aldrich 406023 Diethylzinc solution 1.0 M in heptane 100ml $159 2024-03-01 Buy
Sigma-Aldrich 256781 Diethylzinc ≥52 wt. % Zn basis 100g $180 2024-03-01 Buy

Properties

Melting point :−28 °C(lit.)
Boiling point :98 °C
Density :1.205 g/mL at 25 °C(lit.)
vapor pressure :16hPa at 20℃
refractive index :n20/D 1.498(lit.)
Flash point :45 °F
storage temp. :0-6°C
solubility :reacts with H2O; msc ethyl ether,petroleum ether, benzene
form :Solution
Specific Gravity :0.740
color :Slightly turbid light brown-gray
Water Solubility :REACTS VIOLENTLY
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,3131
BRN :3587207
Dielectric constant :2.5(20℃)
CAS DataBase Reference :557-20-0(CAS DataBase Reference)
NIST Chemistry Reference :Diethylzinc(557-20-0)
EPA Substance Registry System :Zinc, diethyl- (557-20-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

It is used in organic synthesis as a source of the ethyl carbanion in addition reactions to carbonyl groups. It is commonly used in combination with diiodomethane as a Simmons-Smith reagent to convert alkenes into cyclopropyl groups. Employed together with a Rh (I) catalyst to prepare α-trifluoromethyl ketones from α,β-unsaturated ketones. Also used a catalyst, an aerospace fuel, and a deacidification agent in paper manufacturing.

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