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ChemicalBook >> CAS DataBase List >> Diphenylphosphoryl azide

Diphenylphosphoryl azide

Diphenylphosphoryl azide price.
  • $10 - $2480
  • Product name: Diphenylphosphoryl azide
  • CAS: 26386-88-9
  • MF: C12H10N3O3P
  • MW: 275.2
  • EINECS:247-644-0
  • MDL Number:MFCD00001987
  • Synonyms:(PHO)2PO-N3;PHOSPHORIC ACID DIPHENYL ESTER AZIDE;PS-DPPA;Diphenylphosphonicazide,97%;DPPA polymer-bound, PS-DPPA;DPPA, Phosphoric acid diphenyl ester azide;DIPHENYLPHOSPHORYL AZIDE;DIPHENYLPHOSPHORYL AZIDE, POLYMER-BOUND
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  • Acrotein
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  • Azepine
  • Biosynth Carbosynth
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  • Matrix Scientific
  • Medical Isotopes, Inc.
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  • ManufacturerAcrotein
  • Product numberAC-2991
  • Product descriptionDiphenylphosphorazidate 97%
  • Packaging100g
  • Price$67.83
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-11294
  • Product descriptionDiphenylazidophosphate 98%
  • Packaging1000g
  • Price$435
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90300
  • Product descriptionDPPA
  • Packaging5g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberO891
  • Product descriptionDPPA;Diphenylphosphorylazide
  • Packaging25g
  • Price$26
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ70097
  • Product descriptionDPPA;Diphenylphosphorylazide
  • Packaging30g
  • Price$31
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90300
  • Product descriptionDPPA
  • Packaging500g
  • Price$218
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberO891
  • Product descriptionDPPA;Diphenylphosphorylazide
  • Packaging1kg
  • Price$494
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12124
  • Product descriptionDiphenylphosphonic azide, 97%
  • Packaging5g
  • Price$24.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12124
  • Product descriptionDiphenylphosphonic azide, 97%
  • Packaging25g
  • Price$93.2
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberA12124
  • Product descriptionDiphenylphosphonic azide, 97%
  • Packaging100g
  • Price$218
  • Updated2024-03-01
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM1051541
  • Product descriptionDIPHENYLPHOSPHORYL AZIDE 95.00%
  • Packaging5MG
  • Price$550
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM1051541
  • Product descriptionDIPHENYLPHOSPHORYL AZIDE 95.00%
  • Packaging1G
  • Price$619.7
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM1051541
  • Product descriptionDIPHENYLPHOSPHORYL AZIDE 95.00%
  • Packaging2.5G
  • Price$796.77
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM1051541
  • Product descriptionDIPHENYLPHOSPHORYL AZIDE 95.00%
  • Packaging5G
  • Price$912.29
  • Updated2021-12-16
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  • ManufacturerAzepine
  • Product numberAZ0001-0393
  • Product descriptionDiphenylphosphoryl azide 98
  • Packaging25g
  • Price$25
  • Updated2021-12-16
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  • ManufacturerAzepine
  • Product numberAZ0001-0393
  • Product descriptionDiphenylphosphoryl azide 98
  • Packaging100g
  • Price$69
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-2991 Diphenylphosphorazidate 97% 100g $67.83 2021-12-16 Buy
AHH MT-11294 Diphenylazidophosphate 98% 1000g $435 2021-12-16 Buy
AK Scientific J90300 DPPA 5g $10 2021-12-16 Buy
AK Scientific O891 DPPA;Diphenylphosphorylazide 25g $26 2021-12-16 Buy
AK Scientific J70097 DPPA;Diphenylphosphorylazide 30g $31 2021-12-16 Buy
AK Scientific J90300 DPPA 500g $218 2021-12-16 Buy
AK Scientific O891 DPPA;Diphenylphosphorylazide 1kg $494 2021-12-16 Buy
Alfa Aesar A12124 Diphenylphosphonic azide, 97% 5g $24.65 2024-03-01 Buy
Alfa Aesar A12124 Diphenylphosphonic azide, 97% 25g $93.2 2024-03-01 Buy
Alfa Aesar A12124 Diphenylphosphonic azide, 97% 100g $218 2024-03-01 Buy
American Custom Chemicals Corporation CHM1051541 DIPHENYLPHOSPHORYL AZIDE 95.00% 5MG $550 2021-12-16 Buy
American Custom Chemicals Corporation CHM1051541 DIPHENYLPHOSPHORYL AZIDE 95.00% 1G $619.7 2021-12-16 Buy
American Custom Chemicals Corporation CHM1051541 DIPHENYLPHOSPHORYL AZIDE 95.00% 2.5G $796.77 2021-12-16 Buy
American Custom Chemicals Corporation CHM1051541 DIPHENYLPHOSPHORYL AZIDE 95.00% 5G $912.29 2021-12-16 Buy
Azepine AZ0001-0393 Diphenylphosphoryl azide 98 25g $25 2021-12-16 Buy
Azepine AZ0001-0393 Diphenylphosphoryl azide 98 100g $69 2021-12-16 Buy

Properties

Boiling point :157 °C/0.17 mmHg (lit.)
Density :1.277 g/mL at 25 °C (lit.)
refractive index :n20/D 1.551(lit.)
Flash point :>230 °F
storage temp. :2-8°C
solubility :Acetonitrile (Slightly), Chloroform (Slightly), Ethyl Acetate (Sparingly)
form :Liquid
Specific Gravity :1.277
color :slightly yellow
Water Solubility :insoluble
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
BRN :2058967
Stability :Stable. Incompatible with acids, strong oxidizing agents.
InChIKey :SORGEQQSQGNZFI-UHFFFAOYSA-N
CAS DataBase Reference :26386-88-9(CAS DataBase Reference)
NIST Chemistry Reference :Diphenylphosphoryl azide(26386-88-9)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Diphenylphosphonic azide acts as a reagent for the synthesis of peptides and phosphoramidates by reacting with amines. It is also used in the preparation of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement. It is involved in pseudohalogen replacement of the azido group by treatment with nucleophilic reagents, such as water, butanol, ammonia, and various amines. Further, it is used as a hydroazidation catalyst for preparation of organoazides.

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